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SAL: Everything we've been
dealing with so far in our
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journey through chemistry has
revolved around stability of
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electrons and where electrons
would rather
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be in stable shells.
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And like all things in life,
if you explore the atom a
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little further you'll realize
that electrons are not the
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only stuff that's going
on in an atom.
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That the nucleus itself has some
interactions, or has some
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instability, that needs to
be relieved in some way.
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That's what we'll talk
a little bit
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about in this video.
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And actually the mechanics of
it are well out of the scope
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of a first-year chemistry
course, but it's good to at
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least know that it occurs.
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And one day when we study the
strong nuclear force, and
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quantum physics, and all the
like, then we can start
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talking about exactly why these
protons and neutrons,
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and their constituent quarks
are interacting
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the way they do.
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But with that said, let's
at least think about the
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different types of ways that a
nucleus can essentially decay.
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So let's say I have a
bunch of protons.
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I'll just draw a couple here.
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Some protons there, and I'll
draw some neutrons.
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And I'll draw them in
a neutral-ish color.
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Maybe let me see, like a
grayish would be good.
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So let me just draw some
neutrons here.
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How many protons do I have?
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I have 1, 2, 3, 4, 5, 6, 7, 8.
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I'll do 1, 2, 3, 4, 5,
6, 7, 8, 9 neutrons.
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And so let's say this is the
nucleus of our atom.
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And remember-- and this is, you
know, in the very first
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video I made about the atom--
the nucleus, if you actually
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were to draw an actual atom--
and it's actually very hard to
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drawn an atom because it has
no well-defined boundaries.
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The electron really could be,
you know, at any given moment,
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it could be anywhere.
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But if you were to say, OK,
where is 90% of the time the
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electron is going to be in?
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You'd say, that's the radius,
or that's the
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diameter of our atom.
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We learned in that very first
video that the nucleus is
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almost an infinitesimal portion
of the volume of this
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sphere where the electron
will be 90% of the time.
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And the neat takeaway there
was that, well, most of
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whatever we look at in life
is just open free space.
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All of this is just
open space.
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But I just want to repeat
that because that little
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infinitesimal spot that we
talked about before, where
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even though it's a very small
part of the fraction of the
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volume of an atom-- it's
actually almost all of its
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mass-- that's what I'm zooming
out to this point here.
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These aren't atoms, these
aren't electrons.
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We're zoomed into the nucleus.
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And so it turns out that
sometimes the nucleus is a
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little bit unstable, and it
wants to get to a more stable
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configuration.
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We're not going to go into the
mechanics of exactly what
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defines an unstable nucleus
and all that.
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But in order to get into a
more unstable nucleus,
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sometimes it emits what's called
an alpha particle, or
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this is called alpha decay.
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Alpha decay.
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And it emits an alpha particle,
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which sounds very fancy.
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It's just a collection of
neutrons and protons.
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So an alpha particle is two
neutrons and two protons.
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So maybe these guys, they just
didn't feel like they'd fit in
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just right, so they're a
collection right here.
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And they get emitted.
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They leave the nucleus.
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So let's just think what
happens to an atom when
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something like that happens.
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So let's just say I have some
random element, I'll just call
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it element E.
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Let's say it has p, protons.
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Actually let me do it in the
color of my protons.
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It has p, protons.
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And then it has its atomic mass
number, is the number of
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protons plus the number
of neutrons.
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And do the neutrons
in gray, right?
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So when it experiences
alpha decay, what
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happens to the element?
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Well, its protons are going
to decrease by two.
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So its protons are going
to be p minus 2.
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And then its neutrons are also
going to decrease by two.
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So its mass number's going
to decrease by four.
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So up here you'll have p minus
2, plus our neutrons minus 2,
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so we're going to
have minus 4.
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So your mass is going to
decrease by four, and you're
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actually going to turn
to a new element.
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Remember, your elements
were defined by
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the number of protons.
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So in this alpha decay, when
you're losing two neutrons and
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two protons, but especially the
protons are going to make
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you into a different element.
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So if we call this element 1,
I'm just going to call it,
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we're going to be a different
element now, element 2.
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And if you think about what's
generated, we're emitting
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something that has two protons,
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and it has two neutrons.
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So that its mass is going to be
the mass of the two protons
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and two neutrons.
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So what are we emitting?
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We're emitting something that
has a mass of four.
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So if you look at, what is two
protons and two neutrons?
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I actually don't have the
periodic table on my
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[? head. ?]
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I forgot to cut and paste
it before this video.
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But it doesn't take you long on
the periodic table to find
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an element that has two protons,
and that's helium.
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It actually has an atomic
mass of four.
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So this is actually a helium
nucleus that gets emitted with
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alpha decay.
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This is actually a
helium nucleus.
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And because it's a helium
nucleus and it has no
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electrons to bounce off its two
protons, this would be a
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helium ion.
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So essentially it has
no electrons.
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It has two protons so it
has a plus 2 charge.
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So an alpha particle is really
just a helium ion, a plus 2
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charged helium ion that is
spontaneously emitted by a
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nucleus just to get to
a more stable state.
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Now that's one type of decay.
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Let's explore the other ones.
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So let me draw another
nucleus here.
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I'll draw some neutrons.
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I'll just draw some protons.
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So it turns out sometimes that
a neutron doesn't feel
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comfortable with itself.
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It looks at what the protons do
on a daily basis and says,
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you know what?
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For some reason when I look into
my heart, I feel like I
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really should be a proton.
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If I were a proton, the entire
nucleus would be a little bit
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more stable.
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And so what it does is, to
become a proton-- remember, a
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neutron has neutral charge.
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So what it does is, it
emits an electron.
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And I know you're saying, Sal,
you know, that's crazy, I
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didn't even know neutrons
had electrons in
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them, and all of that.
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And I agree with you.
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It is crazy.
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And one day we'll study
all of what exists
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inside of the nucleus.
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But let's just say that it
can emit an electron.
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So this emits an electron.
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And we signify that with its--
roughly its mass is zero.
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We know an electron really
doesn't have a zero mass, but
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we're talking about
atomic mass units.
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If the proton is one, an
electron is 1/1,836 of that.
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So we just round it.
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We say it has a mass of zero.
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Its mass really isn't zero.
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And its charge is minus 1.
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It's atomic, you can kind
of say its atomic
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number's minus 1.
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So it emits an electron.
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And by emitting an electron,
instead of being neutral, now
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it turns into a proton.
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And so this is called
beta decay.
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And a beta particle is really
just that emitted electron.
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So let's go back to our little
case of an element.
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It has some number of protons,
and then it has
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some number of neutrons.
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So you have the protons and
the neutrons, then you get
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your mass number.
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When it experiences beta
decay, what happens?
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Well, are the protons changed?
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Sure, we have one more proton
than we had before.
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Because our neutron
changed into one.
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So now our protons are plus 1.
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Has our mass number changed?
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Well let's see.
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The neutrons goes down
by one but your
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protons go up to by one.
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So your mass number
will not change.
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So it's still going
to be p plus N.
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so your mass stays the same,
unlike the situation with
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alpha decay, but your
element changes.
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Your number of protons
changes.
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So now, once again, you're
dealing with a new element in
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beta decay.
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Now, let's say we have
the other situation.
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Let's say we have a situation
where one of these protons
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looks at the neutrons and
says, you know what?
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I see how they live.
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It's very appealing to me.
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I think I would fit in better,
and our community of particles
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within the nucleus would
be happier if
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I too were a neutron.
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We'd all be in a more
stable condition.
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So what they do is, that little
uncomfortable proton
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has some probability of
emitting-- and now this is a
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new idea to you-- a positron,
not a proton.
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It emits a positron.
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And what's a positron?
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It's something that
has the exact
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same mass as an electron.
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So it's 1/1836 of the
mass of a proton.
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But we just write a zero there
because in atomic mass units
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it's pretty close to zero.
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But it has a positive charge.
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And it's a little confusing,
because they'll
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still write e there.
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Whenever I see an e, I
think an electron.
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But no, they say e because it's
kind of like the same
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type of particle, but instead
of having a negative charge,
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it has a positive charge.
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This is a positron.
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And now we're starting to get
kind of exotic with the types
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of particles and stuff
we're dealing with.
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But this does happen.
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And if you have a proton that
emits this particle, that
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pretty much had all of its
positive charge going with it,
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this proton turns
into a neutron.
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And that is called positron
emission.
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Positron emission is usually
pretty easy to figure out what
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it is, because they call
it positron emission.
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So if we start with the same E,
it has a certain number of
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protons, and a certain
number of neutrons.
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What's the new element
going to be?
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Well it's going to lose
a proton. p minus 1.
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And that's going to be turned
into a neutron.
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So p is going to
go down by one.
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N is going to go up by one.
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So that the mass of the whole
atom isn't going to change.
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So it's going to be p plus N.
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But we're still going to have
a different element, right?
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When we had beta decay,
we increased
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the number of protons.
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So we went, kind of, to the
right in the periodic table or
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we increased our, well,
you get the idea.
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When we do positron emission,
we decreased
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our number of protons.
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And actually I should
write that here in
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both of these reactions.
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So this is the positron
emission, and I'm left over
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with one positron.
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And in our beta decay, I'm left
over with one electron.
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They're written the
exact same way.
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You know this is an electron
because it's a minus 1 charge.
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You know this is a positron
because it
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has a plus 1 charge.
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Now there's one last
type of decay that
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you should know about.
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But it doesn't change the number
of protons or neutrons
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in a nucleus.
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But it just releases a ton of
energy, or sometimes, you
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know, a high-energy proton.
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And that's called gamma decay.
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And gamma decay means that these
guys just reconfigure
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themselves.
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Maybe they get a little
bit closer.
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And by doing that they release
energy in the form of a very
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high wavelength electromagnetic
wave. Which is
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essentially a gamma, you could
either call it a gamma
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particle or gamma ray.
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And it's very high energy.
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Gamma rays are something you
don't want to be around.
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They're very likely
to maybe kill you.
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Everything we did, I've said
is a little theoretical.
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Let's do some actual problems,
and figure out what type of
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decay we're dealing with.
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So here I have 7-beryllium
where seven
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is its atomic mass.
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And I have it being converted
to 7-lithium So
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what's going on here?
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My beryllium, my nuclear mass
is staying the same, but I'm
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going from four protons
to three protons.
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So I'm reducing my number
of protons.
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My overall mass hasn't
changed.
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So it's definitely
not alpha decay.
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Alpha decay was, you know,
you're releasing a whole
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helium from the nucleus.
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So what am I releasing?
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I'm kind of releasing one
positive charge, or I'm
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releasing a positron.
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And actually I have this
here in this equation.
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This is a positron.
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So this type of decay of
7-beryllium to 7-lithium is
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positron emission.
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Fair enough.
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Now let's look at
the next one.
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We have uranium-238 decaying
to thorium-234.
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And we see that the atomic mass
is decreasing by 4, minus
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4, and you see that your atomic
numbers decrease, or
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your protons are decreasing,
by 2.
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So you must be releasing,
essentially, something that
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has an atomic mass of four,
and a atomic number
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of two, or a helium.
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So this is alpha decay.
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So this right here is
an alpha particle.
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And this is an example
of alpha decay.
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Now you're probably saying, hey
Sal, wait, something weird
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is happening here.
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Because if I just go from 92
protons to 90 protons, I still
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have my 92 electrons out here.
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So wouldn't I now have
a minus 2 charge?
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And even better, this helium I'm
releasing, it doesn't have
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any electrons with it.
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It's just a helium nucleus.
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So doesn't that have
a plus 2 charge?
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And if you said that, you would
be absolutely correct.
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But the reality is that right
when this decay happens, this
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thorium, it has no reason
to hold on to those two
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electrons, so those two
electrons disappear and
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thorium becomes neutral again.
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And this helium, likewise,
it is very quick.
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It really wants two electrons
to get stable, so it's very
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quick to grab two electrons out
of wherever it's bumping
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into, and so that
becomes stable.
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So you could write
it either way.
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Now let's do another one.
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So here I have iodine.
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Let's see what's happening.
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My mass is not changing.
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So I must just have protons
turning into neutrons or
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neutrons turning into protons.
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And I see here that I
have 53 protons, and
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now I have 54 protons.
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So a neutron must have
turned into a proton.
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A neutron must have
gone to a proton.
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And the way that a neutron
goes to a proton is by
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releasing an electron.
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And we see that in this
reaction right here.
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An electron has been released.
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And so this is beta decay.
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This is a beta particle.
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And that same logic holds.
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You're like, hey wait, I just
went from 53 to 54 protons.
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Now that I have this extra
proton, won't I have a
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positive charge here?
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Well you would.
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But very quickly this might--
probably won't get these exact
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electrons, there's so many
electrons running around-- but
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it'll grab some electrons from
some place to get stable, and
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then it'll be stable again.
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But you're completely right in
thinking, hey, wouldn't it be
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an ion for some small
amount of time?
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Now let's do one more.
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So we have to 222-radon-- it
has atomic number of 86--
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going to 218-polonium, with
atomic number of 84.
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And this actually is an
interesting aside.
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Polonium is named after Poland,
because Marie Curie,
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she-- At the time Poland, this
was at the turn of the last
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century, around the end of the
1800's, Poland didn't exist as
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a separate country.
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It was split between Prussia,
Russia, and Austria.
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And they really wanted let
people know that, hey, you
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know, we think we're
one people.
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So they discovered that when,
you know, radon decayed it
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formed this element.
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And they named it after their
motherland, after Poland.
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It's the privileges of
discovering new elements.
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But anyway, back
to the problem.
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So what happened?
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Our atomic mass went
down by four.
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Our atomic number went
down by two.
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Once again, we must have
released a helium particle.
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A helium nucleus, something
that has an atomic mass of
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four, and an atomic
number of two.
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And so there we are.
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So this is alpha decay.
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We could write this as
a helium nucleus.
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So it has no electrons.
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We could even say immediately
that this would have a
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negative charge, but
then it loses