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lib.utexas.edu/.../Lewis_Symbols.mp4

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    Hi everyone. In this video we're
    going to discuss Lewis Symbols,
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    but in order to do that properly
    we absolutely need to review
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    valence electrons.
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    So for valence electrons, if you recall,
    they are your outermost electrons.
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    So if I were to draw an atom I would
    have to start with a nucleus.
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    So the nucleus is at the very center,
    that's where your protons
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    and your neutrons are stored.
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    It is tiny, it is miniscule,
    it is very very small.
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    So what's cool about an atom is its
    very first shell,
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    so the first one that's right around
    the nucleus,
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    that one has two electrons in it
    so we'll just put one here and one here,
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    but because the nucleus is so small,
    that first shell is also just so tiny
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    that it can be very tightly compact aound
    the nucleus.
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    It's so small that it can actually
    only hold two electrons,
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    because from there on out,
    every single other shell around it
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    wants to have eight electrons in it
    and so it will just keep growing
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    and growing and every single shell
    will have eight electrons.
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    So now if you recall, we're talking
    about this in the context of
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    valence electrons.
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    So for my example here, I have a
    nuclus in the center and I have
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    one, two, three shells around it.
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    So there first two, this one and this
    one, these are considered your core shells.
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    They host your core electrons so they
    hold on very tight to the nucleus,
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    but on the outside here, we have
    our outermost shell and this is the one
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    that houses our valence electrons.
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    So when we go to a periodic table
    and try to determine the number of
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    valence electrons, we're actually talking
    about the electrons that are sitting
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    in the outermost shell.
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    So now what's really neat about this
    is because we have an inner shell
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    that's so small and only houses
    two electrons,
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    we actually have to kind of manipulate
    the periodic table when
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    we're determining valence electrons
    on our own accord.
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    So what we're going to do here is
    look at our periodic table and specifically
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    look at this very first row.
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    So we said it can only have two electrons
    in its outermost shell and so
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    what we need to do is just come over here
    and we're going to actually move helium.
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    So I'm going to put it right here
    above this second group and we're
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    going to cross out helium over here.
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    So now what I'm going to do is go
    starting from the left,
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    we're going to go across and number
    our valence electrons.
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    So for this first group,
    our alkali metals,
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    they only have one valence electron,
    just one.
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    So if were we to draw it out in
    our diagram,
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    here is our nucleus, there's our shell,
    they have just one electron
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    sitting in the outermost.
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    Then we go to the second group,
    our alkali earth metals.
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    They have two valence electrons.
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    So one and two, and so on and
    so forth.
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    So we go to Boron which has three,
    then four, five, six, seven, and eight.
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    Hopefully this is all a review,
    but we need to understand that in order
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    to actually draw our Lewis symbols.
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    So let's start off with hydrogen.,
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    Hydrogen has the symbol H and we know,
    because we just discussed it,
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    that hydrogen has one valence electron.
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    It's sitting here in the first group.
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    So I'm going to come down here and
    just draw it out.
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    So this is a Lewis symbol for hydrogen.
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    I'm saying that it has one valence
    electron.
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    So let's say I go down in the
    alkali metals and go to lithium.
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    Here's lithium. It also has just one
    valence electron so I would draw it
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    in the same manner as hydrogen.
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    We can go on and on and on
    with sodium and potassium and rubidium,
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    but essentially you just draw
    one electron to the side of it.
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    So let's move on the second group,
    our alkali earth metals.
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    So let's start with helium here,
    and remember we moved helium.
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    So now this is the only tricky part about
    Lewis symbols.
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    The first two dots always go together.
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    So remember how we said that
    we can have two electrons
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    in that innermost shell?
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    That's why.
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    So we draw it out here with the
    two electrons next to each other
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    so helium has two dots.
    Boom, boom. Just like that.
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    Let's go to the next one, Beryllium.
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    So we have berylium here.
    Berylium also has two dots.
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    One and two. Two valence electrons,
    you always draw the first two together,
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    and we could keep going.
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    Magnesium has two,
    one and two.
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    So let's keep going to Boron.
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    Boron has three valence electrons.
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    Remember, the first two always go
    together -- one two.
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    For the third one you can put it
    anywhere you want.
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    It could go here, it could go here,
    or it could go here.
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    It doesn't matter where you go,
    but you just have to be consistent.
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    Oh you need to erase.
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    And you can only have three total.
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    So you have two together and then three
    on the outside.
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    We would do the same thing for aluminum
    and then so on and so forth.
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    Okay? Now let's go to carbon.
    Carbon has four valence electrons.
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    So one, two go together.
    The rest, it doesn't matter.
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    Three and four. I could have put one
    up here in this spot, it doesn't matter,
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    we just want to be consistent and only
    have four total.
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    And so now we have nitrogen.
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    NItrogen has five valence electrons so
    one, two, three, four, five.
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    Again, it doesn't matter where you
    put them, it just matters that the
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    first two go together.
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    So now for oxygen I could start
    down here.
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    One, two, then you just go around.
    Three, four, five --
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    I have one more valence electron so
    you just have to double up.
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    It doesn't matter where, just pick one
    and double up.
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    Then fluorine, that's seven, so one,
    two, three, four, five, six, and seven.
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    Okay for neon, our first noble gas,
    we have neon here, we go
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    one, two, three, four, five, six,
    seven, and eight.
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    Okay, so it has eight electrons,
    they're all together.
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    As long as you keep the first two
    together that's all that matters.
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    Alright, now I'm going to draw out some
    for silicon and I want you
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    to try to decide which is
    the correct answer.
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    So for silicon, we know it has
    four valence electrons,
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    it's positioned right underneath carbon,
    here it is, so four valence electrons.
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    So let's draw out three
    different structures.
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    You're either going to answer multiple
    choice answer A for this,
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    so it's going to look like this one,
    answer B is if you think silicon
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    looks like this.
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    And answer C is if you think silicon
    looks like this.
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    Alright, did you get an answer?
    Hopefully you picked answer C
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    because that's absolutely correct.
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    In order to do this, all you had to do
    is draw the first two electrons together,
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    one, two, and then three, four.
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    It doesn't matter where you put them,
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    this would have also been a
    correct answer.
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    So the last thing I want to do is
    introduce one more piece of information
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    which is called a lone pair of electrons.
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    Now, some people will refer to it
    as a lone pair,
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    some people will write it out as l.p.,
    but all of it means the same thing.
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    It is just saying that you have two
    electrons on some kind of symbol
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    so here' s your thing.
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    Here's Silicon, two electrons that
    are together,
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    they're a pair of electrons so they're
    sitting like this.
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    If I were to draw an energy level,
    I would have one electron here
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    and one electron here.
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    I don't expect you to know what
    this means, but just know that
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    those two first electrons go together.
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    Remember, here's your nucleus,
    here's your inner shell,
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    here's one, here's two.
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    So it's just two electrons that are
    together paired up in an energy level
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    and so that's why we put these
    together like this.
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    Right, we put the first two together.
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    This is considered a lone pair of electrons.
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    Anytime you have two electrons together,
    if this one was a correct symbol over here
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    which it is not, this technically has
    one, two lone pairs of electrons
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    so that's how you count a pair.
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    So I want to ask you a quick question.
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    How many lone pairs do you think
    sulfur has?
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    Okay, we're just looking for the number
    of lone pairs. Go.
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    Alright, did we get an answer,
    hopefully you did.
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    So the first thing you had to do was
    go to your periodic table
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    and find sulfur so we're going to go
    all way up the top and sulfur sits
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    right underneath oxygen and so
    it has six valence electrons
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    so we'll go all the way down here.
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    SO the six valence electrons,
    we have to draw that out.
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    First two go together, one two,
    three, four, five, and six.
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    And so now all we're doing is looking for
    two electrons that are grouped together
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    so here's one lone pair and
    here's two lone pairs.
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    So hopefully put the answer two because
    that's correct.
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    Take care of yourself, drink water,
    and have a great day.
Title:
lib.utexas.edu/.../Lewis_Symbols.mp4
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