this is a dynamic climbing rope one can take hundreds of these massive Falls and it will still provide a soft Landing for the climber Now Let's ignore the blue protective shift and pull out the core so this white strands is the core of the Rope which is responsible for majority of rope's strength if I would untwist the core strand eventually I would get to this thing which is called a multi-filament and if I would dig deeper and try to separate the smallest part of the Rope I would get to a single filament which I can barely see so this is a single filament so this filament is about 10 times thinner than the human hair and there is about 50 to 80 000 of them in a single rope and all of them run across entire length of the Rope now during the fall this filaments stretch but also they slide past each other which creates friction and this friction helps to dampen the impact however if we would make a rope wet water on the surface of the filaments would act as a lubricant this would allow the filaments to slide easier past each other which would reduce the dampening effect also you can probably imagine that as I want to stretch the Rope out it needs to shrink in diameter however if the Rope is full of water in order to shrink in diameter first it needs to spit the water out however if the impact is hard enough the water cannot Escape faster it's like when you belly flop on the water and the water doesn't have enough time to flow around your body and things get even more interesting from here if we would look deeper deep deep inside the filament we would find this but don't worry the only thing you need to know that this is a monomer which joins together to form a polymer chain and this chain can be very long very very long which is really great for making filament fiber and this is where things get interesting notice that some parts of this fiber are arranged neatly in order these parts are called crystalline and they have polymer chains packed so close together that they form an attraction for each other and this happens because hydrogen from one chain really likes the oxygen from the other chain so all of this makes these parts really strong with which is great for the strength of the Rope however it also makes these parts really stiff which is not so great when you want your dynamic rope to stretch and that's what these other parts that look like spaghettis are four they are called amorphous and they have much bigger gaps between the chains which allows them to stretch so when the force is applied on the fiber these spaghetti Parts stretch and the crystalline Parts provide the strength you can probably imagine that a very stiff rope wouldn't be great for climbing but neither the Rope which would stretch too much because when I fall I want to land not on the ground so by controlling the ratio between spaghettis and crystalline Parts rope manufacturers can create this great strength but at the same time perfect Force absorption which is quite impressive now remember I said that hydrogen really likes the oxygen guess what else has a lot of hydrogen and oxygen that's right water good news is that water cannot really penetrate into the crystalline parts of the fiber because the chains there are very packed close together already however spaghetti Parts have gaps and that allows water to come in and bond to the chains and this bonding increases the distance between the chains and it also weakens the intermolecular attraction so now if the the force is applied when the fiber is wet spaghettis might stretch more than what they are capable to recover from and that might damage the entire structure of the fiber but all of that is in theory so let's see if that theory applies to real world climbing situations [Music] and if you're wondering who goes climbing in the rain well this was my birthday and we came up with a brilliant idea to climb 34 routes in a day and half of the day was raining so yeah let's say I have some wet experiences but my anecdotal experiences are not science and to do proper science I needed to go to the place where the ropes are properly tested [Music] [ __ ] there's a lot coming out [Music] that's a lot and before we begin a strange fact I checked a lot of user manuals of dynamic climbing ropes from various Brands and about half of them have various warnings about wet drops however the other half doesn't mention anything hmm okay so here is the question will dry rope cause harder catch on realistic fault scenario well we would say over time yes in the beginning probably not so you mean on a first fall maybe not yes and on the repeated Falls probably yes exactly that's not my first statement made now since we wanted to mimic real world scenarios and heartfalls rarely exceed 4 kilonewtons we needed to modify the drop tower to produce the forces between three and four kilonewtons so we overshoot yes we did buy a lot [Music] okay which took a bit of adjustment on this old drop tower Mammoth actually has a way more advanced drop tower which I already had a pleasure to use when we were testing the cut resistance of the ropes which was super interesting yeah that's easier with the other one because it works electronically you can put in the number where you want to go and then it's aligns it by itself but we are not allowed to use it not for the water it doesn't like water yeah so this one doesn't like the water this one also doesn't like weather no as soon as these get wet rust will appear off the wall and then friction has a big influence on the yeah but this one we don't use this for any development or production control yeah that's why we are allowed to make it wet exactly 4.11 [Music] I've heard you're going like oh the frustration and not only we needed to make sure that our samples are between three and four kilonewtons but also that each of them is as similar as possible how is it going we have a method of how we can always make the nuts equal later we will have fun it's a group activity it's a team building yes how many samples do we need depends on you how many samples do we need depends on how many people we have making them [Music] so what's going on equal length is equal everything is equal having samples as similar as possible was actually really important because as Adriana said textiles is a very tricky and Moody raw material to work with Moody it's very moody yes so although we cannot control the mood of the Rope but in order to make the nice statistics that you're gonna see later in this video we needed to try our best too long so basically we are massaging back and forth to get uh yeah it's what we in German call it Sisyphus are bite no we got it you think so if not it's time for lunch either we succeed or we eat everybody click three points yeah when I was editing this I thought wow if you ever wondered how Geeks are celebrating life this is a prime example anyway the next question was is our test setup repeatable meaning will we get second fall to be close to the first one if we don't get that then we five hours more don't make a night session work till five and then you go bouldering we have time limit because we need to go bouldering because we need to completely very nice that's very good very Swiss accurate our setup was working really well and now we needed to collect a lot of data this might take if we wait three minutes and we do five Falls that's 15 minutes just waiting times three times six fifteen I the eyes are getting bigger and bigger and here are the results if we average all the samples we get the Baseline of how the force is increasing with every fall which shows that rope doesn't have enough time to fully recover so let's see what happens when the ropes are wet look how much air is coming out all the air is escaping from the Rope during the fall the water will be trying to escape trying to blast out of Europe we wanted to do three different tests where the ropes were soaked for 1 5 and 15 minutes and what was interesting that fully submerging the Rope for just one minute was enough to almost completely saturate the Rope meaning that soaking for longer did not add any extra weight and after we dropped all the wet samples and enjoyed the splashing of the water everywhere [Laughter] oh my God here are the results since the difference in water absorption was minimal the forces were actually very similar and if we take the average of all the wet samples we can see that the first fall was only slightly harder however the difference increases with the subsequent false you know it's combining everything to family so statistically significant very good today we made a page science a little future me Interruption since I got more information the peak forces that we measured obviously do contribute to how hard the catch will be for the climber however it's not the only Factor the big Force to the climber usually happens around this moment but even on the hardest Falls this moment is not hard enough for the human body to be a problem what is the problem however is how hard the climber will hit the wall as I mentioned earlier as the Rope is stretching the filaments are rubbing against each other which dampens the energy and and if the Rope would be able to absorb all the energy during the fall it would stretch and then stop however that's not what happens on hard Falls normally the Rope will act like a spring it will stretch and then bounce back that bounce back usually creates more energy going towards the wall and if the Rope is wet the filaments are sliding easier past each other which reduces the dampening effect so the bounce back into the wall should be harder so I was really curious to test this however this requires more advanced testing facilities but luckily after I left Mahmoud did this test in another facility and sent me the results here is the force graph where the initial Peak was said to be around 3.6 kilonewtons and after that we can see how the Rope bounces couple of times now in the case of the wet rope the peak is only slightly higher however the spring effect is much higher and this is the same graph after five consecutive Falls the initial Peak was 23 percent harder however the bounce was much harder so the spring effect was much bigger alright so far we confirmed that wet robes might cause harder Falls but also according to the theory wet drops might lead to some permanent damage to the Rope let's see so we left the last rope hanging overnight so technically now it's dry and um and rested so we dropped this rope once again and the fall was harder compared to the Baseline which definitely hints that there was some permanent damage done to the Rope alright so far so good and there was two more experiments I wanted to make first of all we did all our tests on classic ropes so I was curious how dried treated ropes would perform on the same tests and in case you don't know dry treated ropes are soaked in certain chemicals that make them more water resistant our dry ropes we add the chemical first to the core so to the strands they get a drop application then we braid the rope together and then we submerge it in a chemical bath and we take it out and we dry it and then you have a dry roll so basically core is separately submerged into chemical and then entire rope now the cooler get a drop application you need just a little drop every every couple seconds is enough to make it uh water resistant interesting and then the entire rope goes into the thing yeah when it's finished so let's see how good that treatment is in practice [Music] so at first we did a lot of drops without water and that allowed us to compare treated tropes with classic ones and it was good to see that treatment has no negative effect when the ropes are dry so let's see if it has a positive effect when the ropes are wet number two number two you want to get the shot of how treated robes Stone bubble or duvet bubble wait maybe I don't want to look it doesn't bubble as much as the other one what if you squeeze it a bit but no squeezing and yes dry treated ropes absorbed significantly less water ah I know what can be the problem that ends I see bubbles coming from the ends a little bit although we sealed the ends but most of the bubbles are coming from the tip of the Rope maybe I'm gonna keep that tip just a little bit out yeah I mean you can always have like little holes where it could get in with these kind of things if it's not seared well in the end you have like a capillary effect of that the water traveled along the fiber okay let's see I'm super curious [Music] wow there was no splash of water and here is the treated rope that we soaked for 15 minutes as you can see there is still barely any water coming out of it and if we would compare this to the classic ropes the difference is huge we're still here collecting the data Never Ending Story how are we feeling to you yeah here stopped for climbing and when it comes to the treated tropes soaking them up to 5 minutes showed no increase in forces however soaking for 15 minutes already was worse but not as bad compared to the classic ropes so dried treated ropes unsurprisingly were performing better in wet conditions however I know that many of you myself included had a question how long does dry treatment stay effective does it wear off so this is a used truck that I used for about a year actively almost climbing every second or every third day so we could get a sample of this yeah that's it this orange rope that I brought is actually perfect for our comparisons because it's exactly the same rope as the one we already tested the only difference is the color at first we did the test without water so that we could compare how much stiffer old rope gets compared to the new one and to my surprise the difference was very minimal one note here is that we selected the test sample from the middle of the rope that part of the Rope usually is the least damaged but that's good to know that if your ends of the Rope are damaged and you chop them off the rest of the Rope should perform really well [Music] yeah oh it's bubbling much more than new ropes yeah and yes old rope absorbed more water however it still performed better compared to the classic rope being new treated rope soaked for five minutes let's see how it how well it served [Laughter] [Music] we actually washed the Rope but you can still see that the water which comes out of it is still grayish a little bit coming out does it hurt so you want to blend my washing machine and this is what happened with the wet old rope the first fall was actually identical which is very nice and then the subsequent folds again had an increase in forces and if we would compare all wet drops this is what we get and the only thing missing here that we had no time to do would be to test old classic robes so yes treated robes do lose their water repellent magic Over time however they still perform better compared to the classic ropes however there is still one very interesting thing to know let's look into water absorption graph again notice that classic crops are almost fully saturated after five minutes however treated tropes even after 15 minutes still have a trend up so then the question is what's the full saturation point of treated ropes so I asked Adriana to do these tests and here are the results turns out that all the ropes were trending to the same around 40 percent level so that means even if your rope is dry treated and you put it under water and you leave it there for long enough I don't know why would you do that but if you would do that eventually all of these tens of thousands of tiny filaments in the Rope would act as capillaries and the water would find its way in and it would probably perform similar to the Rope being not treated now before some of you will become hydrophobic let me add a couple of things yes wet ropes are significantly heavier which sucks when you're climbing and they might wear down quicker both from false and from abrasion which sucks to your wallet also there is a theory that They are thicker with swell from water let's see I soaked this rope for a few hours this is supposed to be 9.8 rope and I'm measuring 11.3 let's see the wet spot okay so I don't see any difference at least on this rope which is worn out and it's already thicker when it's nominal value yeah so I didn't want to leave my fellow climbers hanging like that so the next day I took a bunch of different used ropes soaked them and measured the thickness and what I found out is that indeed some of the robes did got thicker like the green decathlon rope for example however other ropes did not change in diameter next I tested how smooth the ropes run through belaying devices and here my findings were mixed again some of the ropes got sticky they became harder to pull through belaying device and more likely to lock the blank device however other ropes got the opposite result they became more slippery as if water would lubricate the billeting device so yes the laying does change with water however it's unclear how how the change will affect Europe and about those other things well honestly it's unlikely that you will climb in such a wet conditions long enough to even have those problems so if your rope got a bit wet well try it but if I would be going to cold wet ice climbing places where people die um yeah maybe having a treated rope reduces the chance of dying this is so hard she put I mean I don't know just like being in a snowy or icy environment it's recommended to have the dry treatment because it's just an extra safety buffer yeah there is one route in Spain which crosses a waterfall in multi-pitch yeah I mean also if you're climb in very humid conditions it's Thailand we go there it's really humid and dry rope makes sense interesting so the little details shall we go to Thailand to do some science research trip all right if you found this video interesting I made the playlist for you where I was nerding with Mammoth Engineers on different topics very interesting topics so thank you Mahmoud for letting me to periodically come over and play with your toys and thank you Adriana for all their rope chemistry explanations and thank you for watching you in the next one