[Script Info]
Title: 
[Events]
Format: Layer, Start, End, Style, Name, MarginL, MarginR, MarginV, Effect, Text
Dialogue: 0,0:00:00.00,0:00:02.84,Default,,0000,0000,0000,,Deyək ki zəif turşum var.
Dialogue: 0,0:00:02.84,0:00:05.77,Default,,0000,0000,0000,,Bunu HA adlandıraq.
Dialogue: 0,0:00:05.77,0:00:12.03,Default,,0000,0000,0000,,A əslində bura qoya biləcəyim bir çox
Dialogue: 0,0:00:12.03,0:00:12.59,Default,,0000,0000,0000,,elementi təmsil edir.
Dialogue: 0,0:00:12.59,0:00:15.34,Default,,0000,0000,0000,,Bu flor yada ammonyak molekulu ola bilər.
Dialogue: 0,0:00:15.34,0:00:17.40,Default,,0000,0000,0000,,Əgər H əlavə etsən bu ammonium olacaq.
Dialogue: 0,0:00:17.40,0:00:20.09,Default,,0000,0000,0000,,Bu xüsusi bir element deyil.
Dialogue: 0,0:00:20.09,0:00:24.17,Default,,0000,0000,0000,,Bu sadəcə turşu yazmağın ümumi qaydasıdır.
Dialogue: 0,0:00:24.17,0:00:31.33,Default,,0000,0000,0000,,Bu tarazlıqdadır,
Dialogue: 0,0:00:31.33,0:00:34.52,Default,,0000,0000,0000,,və bunu çox görmüsüz.
Dialogue: 0,0:00:34.52,0:00:36.85,Default,,0000,0000,0000,,Bunların hamısı sulu məhluldadır.
Dialogue: 0,0:00:39.35,0:00:42.08,Default,,0000,0000,0000,,Bu proton birləşdirici əsasın və molekulun
Dialogue: 0,0:00:42.08,0:00:44.30,Default,,0000,0000,0000,,arasında tullanır.
Dialogue: 0,0:00:44.30,0:00:44.82,Default,,0000,0000,0000,,Mənfi.
Dialogue: 0,0:00:44.82,0:00:48.51,Default,,0000,0000,0000,,Əsas tarazlığıda yazmış ola bilərdik,
Dialogue: 0,0:00:48.51,0:00:52.37,Default,,0000,0000,0000,,birləşdirici əsasın ayrıla biləcəyini və
Dialogue: 0,0:00:52.37,0:00:55.77,Default,,0000,0000,0000,,sudan hidrogen ayıraraq OH yarada
Dialogue: 0,0:00:55.77,0:00:57.17,Default,,0000,0000,0000,,biləcəyini deməilyik.
Dialogue: 0,0:00:57.17,0:00:59.97,Default,,0000,0000,0000,,Amma bu videonun əsas məqsədi deyil.
Dialogue: 0,0:00:59.97,0:01:03.16,Default,,0000,0000,0000,,Burada tarazlığa bir şəkildə təsir etsək
Dialogue: 0,0:01:03.16,0:01:06.58,Default,,0000,0000,0000,,nə ola biləcəyini düşünəciyik.
Dialogue: 0,0:01:06.58,0:01:09.78,Default,,0000,0000,0000,,Bildiyiniz kimi, Chatelliers
Dialogue: 0,0:01:09.78,0:01:12.41,Default,,0000,0000,0000,,prinsipinə görə, tarazlığı gərginləşdirsək
Dialogue: 0,0:01:12.41,0:01:15.85,Default,,0000,0000,0000,,tarazlıq bu stresi aradan
Dialogue: 0,0:01:15.85,0:01:18.93,Default,,0000,0000,0000,,qaldıracaq şəkildə hərəkət edir.
Dialogue: 0,0:01:18.93,0:01:28.76,Default,,0000,0000,0000,,Deyək ki bu sistemə əlavə etdiyim stresdi.
Dialogue: 0,0:01:28.76,0:01:30.87,Default,,0000,0000,0000,,Fərqli rəng edək.
Dialogue: 0,0:01:30.87,0:01:33.99,Default,,0000,0000,0000,,Güclü əsas əlavə edəcəm.
Dialogue: 0,0:01:33.99,0:01:36.10,Default,,0000,0000,0000,,Bu çox tünddür.
Dialogue: 0,0:01:36.10,0:01:39.49,Default,,0000,0000,0000,,NaOH əlavə edəcəm.
Dialogue: 0,0:01:39.49,0:01:42.24,Default,,0000,0000,0000,,Bilirik ki, bu maye mühitə qoyduqda
Dialogue: 0,0:01:42.24,0:01:45.05,Default,,0000,0000,0000,,güclü əsasdır, natrium olan hissəsi\Nbirləşmir,
Dialogue: 0,0:01:45.05,0:01:47.57,Default,,0000,0000,0000,,ən əsası isə məhluldakı OH hidrogeni
Dialogue: 0,0:01:47.57,0:01:51.03,Default,,0000,0000,0000,,uzaqlaşdırmaq istəyir.
Dialogue: 0,0:01:51.03,0:01:54.86,Default,,0000,0000,0000,,Məhlula OH əlavə etdikdə hər mola nə
Dialogue: 0,0:01:54.86,0:01:58.72,Default,,0000,0000,0000,,olacaq, sadəcə mol yox, əlavə etdiyiniz
Dialogue: 0,0:01:58.72,0:02:03.25,Default,,0000,0000,0000,,hər molekula nə olacaq, bunlar hidrogen
Dialogue: 0,0:02:03.25,0:02:05.90,Default,,0000,0000,0000,,molekullarını götürəcəklər.
Dialogue: 0,0:02:05.90,0:02:06.19,Default,,0000,0000,0000,,Düzdü?
Dialogue: 0,0:02:06.19,0:02:10.36,Default,,0000,0000,0000,,Məsələn, əgər məhlulda 1 mol hidrogen
Dialogue: 0,0:02:10.36,0:02:15.14,Default,,0000,0000,0000,,molekulları varsa və məhlula 1 mol
Dialogue: 0,0:02:15.14,0:02:18.27,Default,,0000,0000,0000,,natrium hidroksit əlavə etdikdə bunlar
Dialogue: 0,0:02:18.27,0:02:19.53,Default,,0000,0000,0000,,hamısı reaksiyaya girəcək.
Dialogue: 0,0:02:19.53,0:02:24.79,Default,,0000,0000,0000,,OH lar H-lar ilə reaksiyaya girəcək və su
Dialogue: 0,0:02:24.79,0:02:27.32,Default,,0000,0000,0000,,yaradacaqlar,və məhlulda yoxa çıxacaqlar.
Dialogue: 0,0:02:27.32,0:02:29.39,Default,,0000,0000,0000,,Əslində yox olmayıb, suya çevriliblər.
Dialogue: 0,0:02:29.39,0:02:32.22,Default,,0000,0000,0000,,Bütün hidrogenlər gedəcəklər.
Dialogue: 0,0:02:32.22,0:02:34.16,Default,,0000,0000,0000,,Yada ən azından ilk hidrogen gedəcək.
Dialogue: 0,0:02:34.16,0:02:36.89,Default,,0000,0000,0000,,1 mol hidrogenlər yox olacaqlar.
Dialogue: 0,0:02:36.89,0:02:39.98,Default,,0000,0000,0000,,Bəs bu reaksiyada nə baş verməliydi?
Dialogue: 0,0:02:39.98,0:02:41.69,Default,,0000,0000,0000,,Bilirik ki,bu tarazlıq reaksiyasıdı
Dialogue: 0,0:02:41.69,0:02:49.47,Default,,0000,0000,0000,,Tarazlıq reaksiyası olduğu və zəif əsas
Dialogue: 0,0:02:49.47,0:02:52.20,Default,,0000,0000,0000,,olduğu üçün hidrogenlər azaldıqca bu
Dialogue: 0,0:02:52.20,0:02:58.13,Default,,0000,0000,0000,,iki məhsuldan daha çox yaradacaq və bu
Dialogue: 0,0:02:58.13,0:03:01.11,Default,,0000,0000,0000,,şəkildə itirilən hidrogənləri tamamlayacaq
Dialogue: 0,0:03:01.11,0:03:03.16,Default,,0000,0000,0000,,
Dialogue: 0,0:03:03.16,0:03:08.92,Default,,0000,0000,0000,,Yəni, hidrogən azaldıqca,
Dialogue: 0,0:03:08.92,0:03:10.70,Default,,0000,0000,0000,,tarazlıq daha da sürətlənəcək.
Dialogue: 0,0:03:10.70,0:03:13.60,Default,,0000,0000,0000,,Bura aşağı düşəcək.
Dialogue: 0,0:03:13.60,0:03:15.77,Default,,0000,0000,0000,,Bura qalxacaq.
Dialogue: 0,0:03:15.77,0:03:17.54,Default,,0000,0000,0000,,Bura isə aşağı az düşəcək.
Dialogue: 0,0:03:17.54,0:03:20.52,Default,,0000,0000,0000,,Bura natrium hidroksit qoyduqda\N
Dialogue: 0,0:03:20.52,0:03:22.27,Default,,0000,0000,0000,,bu bütün hidrogənləri götürəcək.
Dialogue: 0,0:03:22.27,0:03:25.93,Default,,0000,0000,0000,,
Dialogue: 0,0:03:25.93,0:03:28.44,Default,,0000,0000,0000,,
Dialogue: 0,0:03:28.44,0:03:31.01,Default,,0000,0000,0000,,Bunlar yox olanda zəif əsas
Dialogue: 0,0:03:31.01,0:03:31.95,Default,,0000,0000,0000,,daha çox ayrılacaq.
Dialogue: 0,0:03:31.95,0:03:36.46,Default,,0000,0000,0000,,Tarazlıq bu istiqamətdə hərəkət edəcək.
Dialogue: 0,0:03:36.46,0:03:38.19,Default,,0000,0000,0000,,Bunların hamısını götürəcək.
Dialogue: 0,0:03:38.19,0:03:41.01,Default,,0000,0000,0000,,Amma tarazlıq bu istiqamətdə hərəkət
Dialogue: 0,0:03:41.01,0:03:43.04,Default,,0000,0000,0000,,edərsə,hidrogenin çoxu dəyişəcəkdir.
Dialogue: 0,0:03:43.04,0:03:46.84,Default,,0000,0000,0000,,Nə düşünürsüz, əgər natrium hidroksidi
Dialogue: 0,0:03:46.84,0:03:49.35,Default,,0000,0000,0000,,suya atsam nə olacaq.
Dialogue: 0,0:03:49.35,0:03:54.47,Default,,0000,0000,0000,,Yəni, NaOH məhlulu hazırlasam,
Dialogue: 0,0:03:54.47,0:03:58.12,Default,,0000,0000,0000,,bu suda tamamən natrium kationlarina və
Dialogue: 0,0:03:58.12,0:04:05.26,Default,,0000,0000,0000,,hidroksit anionlarına ayrılacaq.
Dialogue: 0,0:04:07.81,0:04:10.54,Default,,0000,0000,0000,,Yəni, əlavə etdiyim natrium hidroksidə
Dialogue: 0,0:04:10.54,0:04:15.32,Default,,0000,0000,0000,,bir anda OH miqdarını artırırıq
Dialogue: 0,0:04:15.32,0:04:18.06,Default,,0000,0000,0000,,və beləcə pH artırmış oluruq
Dialogue: 0,0:04:18.06,0:04:20.09,Default,,0000,0000,0000,,düzdü?
Dialogue: 0,0:04:20.09,0:04:20.47,Default,,0000,0000,0000,,Xatırla.
Dialogue: 0,0:04:20.47,0:04:25.51,Default,,0000,0000,0000,,OH miqdarını artırdıqda,
Dialogue: 0,0:04:25.51,0:04:27.94,Default,,0000,0000,0000,,pOH azalacaq, düzdü?
Dialogue: 0,0:04:27.94,0:04:31.98,Default,,0000,0000,0000,,
Dialogue: 0,0:04:31.98,0:04:34.70,Default,,0000,0000,0000,,Yəni, əgər OH artsa,pOH azalacaq
Dialogue: 0,0:04:34.70,0:04:38.22,Default,,0000,0000,0000,,və pH artacaq.
Dialogue: 0,0:04:38.22,0:04:44.17,Default,,0000,0000,0000,,OH bunu təməl edir\N
Dialogue: 0,0:04:44.17,0:04:46.53,Default,,0000,0000,0000,,Və pH da yüksək təməldir.
Dialogue: 0,0:04:46.53,0:04:49.36,Default,,0000,0000,0000,,Əgər, bundan bir mol varsa, pH 14 olacaq.
Dialogue: 0,0:04:49.36,0:04:51.79,Default,,0000,0000,0000,,Əgər,güclü əsas yox, güclü turşu varsa,
Dialogue: 0,0:04:51.79,0:04:54.49,Default,,0000,0000,0000,,pH 0 olacaq.
Dialogue: 0,0:04:54.49,0:04:56.30,Default,,0000,0000,0000,,Ümid edirəm ki, bunu artıq anlayırsız
Dialogue: 0,0:04:56.30,0:04:59.86,Default,,0000,0000,0000,,əgər qarışdırırsızsa, logaritmalarla
Dialogue: 0,0:04:59.86,0:05:02.26,Default,,0000,0000,0000,,çalışsaz, sonunda biləcəksiz.
Dialogue: 0,0:05:02.26,0:05:05.78,Default,,0000,0000,0000,,Nəysə, mövzuya dönək, əgər bunu suda etsəz
Dialogue: 0,0:05:05.78,0:05:09.15,Default,,0000,0000,0000,,super yüksək pH olacaq, çünki
Dialogue: 0,0:05:09.15,0:05:11.29,Default,,0000,0000,0000,,OH qatılığını çox artırırıq.
Dialogue: 0,0:05:11.29,0:05:15.22,Default,,0000,0000,0000,,Amma əgər, natrium hidroksidi suya deyil
Dialogue: 0,0:05:15.22,0:05:19.75,Default,,0000,0000,0000,,digər məhlula, zəif turşu və birləşdirici
Dialogue: 0,0:05:19.75,0:05:24.40,Default,,0000,0000,0000,,əsas olan məhlula əlavə etsək
Dialogue: 0,0:05:24.40,0:05:25.69,Default,,0000,0000,0000,,Nə olacaq?
Dialogue: 0,0:05:25.69,0:05:28.32,Default,,0000,0000,0000,,OH reaksiya girib bütün hidrogenləri
Dialogue: 0,0:05:28.32,0:05:29.09,Default,,0000,0000,0000,,götürəcək.
Dialogue: 0,0:05:29.09,0:05:31.74,Default,,0000,0000,0000,,Amma burda əlavə hidrogen qaynağı var
Dialogue: 0,0:05:31.74,0:05:33.30,Default,,0000,0000,0000,,və çoxlu hidrogen əmələ gətirir.
Dialogue: 0,0:05:33.30,0:05:35.20,Default,,0000,0000,0000,,İtirilənlərin yerini dolduracaq.
Dialogue: 0,0:05:35.20,0:05:38.76,Default,,0000,0000,0000,,Ona görə stress pis deyil.
Dialogue: 0,0:05:38.76,0:05:42.67,Default,,0000,0000,0000,,Natrium hidroksidi suya atdığınızda
Dialogue: 0,0:05:42.67,0:05:44.13,Default,,0000,0000,0000,,pH artmışdı.
Dialogue: 0,0:05:44.13,0:05:47.15,Default,,0000,0000,0000,,
Dialogue: 0,0:05:47.15,0:05:50.69,Default,,0000,0000,0000,,
Dialogue: 0,0:05:50.69,0:05:52.93,Default,,0000,0000,0000,,
Dialogue: 0,0:05:52.93,0:05:54.80,Default,,0000,0000,0000,,
Dialogue: 0,0:05:54.80,0:05:57.39,Default,,0000,0000,0000,,
Dialogue: 0,0:05:57.39,0:06:00.50,Default,,0000,0000,0000,,
Dialogue: 0,0:06:00.50,0:06:03.66,Default,,0000,0000,0000,,
Dialogue: 0,0:06:03.66,0:06:04.54,Default,,0000,0000,0000,,
Dialogue: 0,0:06:04.54,0:06:05.62,Default,,0000,0000,0000,,
Dialogue: 0,0:06:05.62,0:06:08.32,Default,,0000,0000,0000,,
Dialogue: 0,0:06:08.32,0:06:12.04,Default,,0000,0000,0000,,
Dialogue: 0,0:06:12.04,0:06:16.36,Default,,0000,0000,0000,,
Dialogue: 0,0:06:16.36,0:06:21.72,Default,,0000,0000,0000,,
Dialogue: 0,0:06:21.72,0:06:25.76,Default,,0000,0000,0000,,
Dialogue: 0,0:06:25.76,0:06:27.64,Default,,0000,0000,0000,,
Dialogue: 0,0:06:27.64,0:06:28.85,Default,,0000,0000,0000,,
Dialogue: 0,0:06:28.85,0:06:30.48,Default,,0000,0000,0000,,
Dialogue: 0,0:06:30.48,0:06:32.83,Default,,0000,0000,0000,,
Dialogue: 0,0:06:32.83,0:06:34.36,Default,,0000,0000,0000,,
Dialogue: 0,0:06:34.36,0:06:36.88,Default,,0000,0000,0000,,
Dialogue: 0,0:06:36.88,0:06:39.02,Default,,0000,0000,0000,,
Dialogue: 0,0:06:39.02,0:06:40.60,Default,,0000,0000,0000,,
Dialogue: 0,0:06:40.60,0:06:42.06,Default,,0000,0000,0000,,
Dialogue: 0,0:06:42.06,0:06:42.47,Default,,0000,0000,0000,,
Dialogue: 0,0:06:42.47,0:06:46.47,Default,,0000,0000,0000,,
Dialogue: 0,0:06:46.47,0:06:47.39,Default,,0000,0000,0000,,
Dialogue: 0,0:06:47.39,0:06:51.46,Default,,0000,0000,0000,,
Dialogue: 0,0:06:51.46,0:06:54.92,Default,,0000,0000,0000,,
Dialogue: 0,0:06:54.92,0:06:58.35,Default,,0000,0000,0000,,
Dialogue: 0,0:06:58.35,0:07:01.53,Default,,0000,0000,0000,,
Dialogue: 0,0:07:05.12,0:07:07.11,Default,,0000,0000,0000,,
Dialogue: 0,0:07:07.11,0:07:09.27,Default,,0000,0000,0000,,
Dialogue: 0,0:07:09.27,0:07:12.51,Default,,0000,0000,0000,,
Dialogue: 0,0:07:12.51,0:07:15.38,Default,,0000,0000,0000,,
Dialogue: 0,0:07:15.38,0:07:19.36,Default,,0000,0000,0000,,
Dialogue: 0,0:07:19.36,0:07:20.45,Default,,0000,0000,0000,,
Dialogue: 0,0:07:20.45,0:07:22.75,Default,,0000,0000,0000,,
Dialogue: 0,0:07:22.75,0:07:25.16,Default,,0000,0000,0000,,
Dialogue: 0,0:07:25.16,0:07:29.35,Default,,0000,0000,0000,,
Dialogue: 0,0:07:29.35,0:07:32.38,Default,,0000,0000,0000,,
Dialogue: 0,0:07:32.38,0:07:33.28,Default,,0000,0000,0000,,
Dialogue: 0,0:07:33.28,0:07:35.67,Default,,0000,0000,0000,,
Dialogue: 0,0:07:35.67,0:07:37.82,Default,,0000,0000,0000,,
Dialogue: 0,0:07:37.82,0:07:40.05,Default,,0000,0000,0000,,
Dialogue: 0,0:07:40.05,0:07:44.28,Default,,0000,0000,0000,,
Dialogue: 0,0:07:44.28,0:07:47.22,Default,,0000,0000,0000,,
Dialogue: 0,0:07:47.22,0:07:49.69,Default,,0000,0000,0000,,
Dialogue: 0,0:07:49.69,0:07:53.37,Default,,0000,0000,0000,,
Dialogue: 0,0:07:53.37,0:07:57.64,Default,,0000,0000,0000,,
Dialogue: 0,0:07:57.64,0:08:00.29,Default,,0000,0000,0000,,
Dialogue: 0,0:08:00.29,0:08:02.93,Default,,0000,0000,0000,,
Dialogue: 0,0:08:02.93,0:08:06.18,Default,,0000,0000,0000,,
Dialogue: 0,0:08:06.18,0:08:08.26,Default,,0000,0000,0000,,
Dialogue: 0,0:08:08.26,0:08:12.76,Default,,0000,0000,0000,,
Dialogue: 0,0:08:12.76,0:08:14.02,Default,,0000,0000,0000,,
Dialogue: 0,0:08:14.02,0:08:17.10,Default,,0000,0000,0000,,
Dialogue: 0,0:08:17.10,0:08:20.42,Default,,0000,0000,0000,,
Dialogue: 0,0:08:20.42,0:08:21.45,Default,,0000,0000,0000,,
Dialogue: 0,0:08:21.45,0:08:24.31,Default,,0000,0000,0000,,
Dialogue: 0,0:08:24.31,0:08:30.15,Default,,0000,0000,0000,,
Dialogue: 0,0:08:30.15,0:08:31.58,Default,,0000,0000,0000,,
Dialogue: 0,0:08:31.58,0:08:33.08,Default,,0000,0000,0000,,
Dialogue: 0,0:08:38.89,0:08:41.78,Default,,0000,0000,0000,,
Dialogue: 0,0:08:41.78,0:08:45.67,Default,,0000,0000,0000,,
Dialogue: 0,0:08:45.67,0:08:46.84,Default,,0000,0000,0000,,
Dialogue: 0,0:08:46.84,0:08:48.99,Default,,0000,0000,0000,,
Dialogue: 0,0:08:48.99,0:08:52.66,Default,,0000,0000,0000,,
Dialogue: 0,0:08:52.66,0:08:54.94,Default,,0000,0000,0000,,
Dialogue: 0,0:08:54.94,0:08:56.43,Default,,0000,0000,0000,,
Dialogue: 0,0:08:56.43,0:08:57.04,Default,,0000,0000,0000,,
Dialogue: 0,0:08:57.04,0:09:00.65,Default,,0000,0000,0000,,
Dialogue: 0,0:09:00.65,0:09:03.88,Default,,0000,0000,0000,,
Dialogue: 0,0:09:03.88,0:09:06.86,Default,,0000,0000,0000,,
Dialogue: 0,0:09:06.86,0:09:11.07,Default,,0000,0000,0000,,
Dialogue: 0,0:09:11.07,0:09:14.42,Default,,0000,0000,0000,,
Dialogue: 0,0:09:14.42,0:09:18.09,Default,,0000,0000,0000,,
Dialogue: 0,0:09:18.09,0:09:19.19,Default,,0000,0000,0000,,
Dialogue: 0,0:09:19.19,0:09:20.09,Default,,0000,0000,0000,,
Dialogue: 0,0:09:20.09,0:09:23.25,Default,,0000,0000,0000,,
Dialogue: 0,0:09:28.44,0:09:33.41,Default,,0000,0000,0000,,
Dialogue: 0,0:09:33.41,0:09:36.45,Default,,0000,0000,0000,,
Dialogue: 0,0:09:36.45,0:09:38.46,Default,,0000,0000,0000,,
Dialogue: 0,0:09:38.46,0:09:41.45,Default,,0000,0000,0000,,
Dialogue: 0,0:09:41.45,0:09:44.58,Default,,0000,0000,0000,,
Dialogue: 0,0:09:44.58,0:09:47.50,Default,,0000,0000,0000,,
Dialogue: 0,0:09:47.50,0:09:50.71,Default,,0000,0000,0000,,
Dialogue: 0,0:09:50.71,0:09:55.09,Default,,0000,0000,0000,,
Dialogue: 0,0:09:55.09,0:10:00.58,Default,,0000,0000,0000,,
Dialogue: 0,0:10:00.58,0:10:03.15,Default,,0000,0000,0000,,
Dialogue: 0,0:10:03.15,0:10:05.17,Default,,0000,0000,0000,,
Dialogue: 0,0:10:05.17,0:10:11.33,Default,,0000,0000,0000,,
Dialogue: 0,0:10:11.33,0:10:14.53,Default,,0000,0000,0000,,
Dialogue: 0,0:10:14.53,0:10:17.62,Default,,0000,0000,0000,,
Dialogue: 0,0:10:17.62,0:10:21.40,Default,,0000,0000,0000,,
Dialogue: 0,0:10:21.40,0:10:25.83,Default,,0000,0000,0000,,
Dialogue: 0,0:10:25.83,0:10:27.74,Default,,0000,0000,0000,,
Dialogue: 0,0:10:27.74,0:10:30.39,Default,,0000,0000,0000,,
Dialogue: 0,0:10:30.39,0:10:32.71,Default,,0000,0000,0000,,
Dialogue: 0,0:10:32.71,0:10:36.02,Default,,0000,0000,0000,,
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