WEBVTT 00:00:00.460 --> 00:00:06.128 Calculate the molarity of a solution prepared by dissolving 9.8 moles of solid 00:00:06.128 --> 00:00:14.675 NaOH, that's sodium hydroxide, in enough water to make 3.62 liters of solution. 00:00:14.675 --> 00:00:17.964 To find molarity, you take moles of solute and 00:00:17.964 --> 00:00:21.734 divide it by liters of solution. 00:00:21.734 --> 00:00:27.188 So to set our equation up here, we have Molarity = moles of solute, 00:00:27.188 --> 00:00:31.057 sodium hydroxide is the solute here cuz it's getting dissolved in water. 00:00:31.057 --> 00:00:36.143 And we have 9.8 moles of that, divided by liters 00:00:36.143 --> 00:00:42.280 of solution, which is 3.62 liters right here. 00:00:42.280 --> 00:00:48.872 So find molarity, 9.8 divided by 3.62, round the answer to 00:00:48.872 --> 00:00:54.659 two significant figures cuz I have 9.8 up here, and I get 2.7. 00:00:54.659 --> 00:00:57.240 What should the units be for this? 00:00:57.240 --> 00:01:04.306 When you find molarity the final answer is in units of molar, capital M. 00:01:04.306 --> 00:01:06.976 So this is 2.7 molar. 00:01:06.976 --> 00:01:11.085 But what 2.7 molar really means is that 00:01:11.085 --> 00:01:16.986 there are 2.7 moles of NaOH, of the solute, 00:01:16.986 --> 00:01:21.701 for every one liter of the solution. 00:01:21.701 --> 00:01:28.022 So 2.7 M, but don't forget that that means 2.7 moles for 00:01:28.022 --> 00:01:33.078 each 1 liter of this solution up here. 00:01:33.078 --> 00:01:39.368 You dissolve 152.5 g of CuCl2, that's copper chloride, 00:01:39.368 --> 00:01:45.210 in water to make a solution with a final volume of 2.25 liters. 00:01:45.210 --> 00:01:47.845 What is it's molarity? 00:01:47.845 --> 00:01:49.541 So, for molarity as you know, 00:01:49.541 --> 00:01:53.082 we wanna take moles of solute divided by the liters of solution. 00:01:53.082 --> 00:01:56.970 CuCl2, copper chloride is also a solute in this case cuz it's getting dissolved in 00:01:56.970 --> 00:01:58.556 the water. 00:01:58.556 --> 00:02:02.943 But the problem doesn't tell us how many moles of copper chloride we have. 00:02:02.943 --> 00:02:06.825 It tells us how many grams of copper chloride we have. 00:02:06.825 --> 00:02:12.784 So 152.5, we can't use that number, instead we have to convert 00:02:12.784 --> 00:02:17.140 this to moles and then we can plug it into the molarity equation. 00:02:17.140 --> 00:02:20.940 So to convert this amount in grams into moles, 00:02:20.940 --> 00:02:25.820 the first thing that we've got to start with is the molar mass of copper chloride. 00:02:25.820 --> 00:02:29.940 And so to find the molar mass of copper chloride, we got to find copper and 00:02:29.940 --> 00:02:36.080 chlorine on the periodic table and take a look at their atomic masses. 00:02:36.080 --> 00:02:40.910 So copper, there is one copper atom in copper chloride. 00:02:40.910 --> 00:02:47.760 So I'll take the molar mass of copper, 63.55, and then there 00:02:47.760 --> 00:02:51.710 are two of these chlorines in copper chloride. 00:02:51.710 --> 00:03:01.247 So I wanna take 2 times the molar mass of chlorine which is 35.44. 00:03:01.247 --> 00:03:04.395 When I add these together, 00:03:04.395 --> 00:03:12.217 I get 134.45 grams 00:03:12.217 --> 00:03:14.600 per 1 mole, okay. 00:03:14.600 --> 00:03:17.330 That's like the molar mass of it. 00:03:17.330 --> 00:03:20.480 Now we're gonna have to use this as a conversion factor, 00:03:20.480 --> 00:03:23.110 to go between grams and moles. 00:03:23.110 --> 00:03:25.200 So remember that when we have conversion factors like this, 00:03:25.200 --> 00:03:27.040 we can always write them in two ways. 00:03:27.040 --> 00:03:29.420 We can write it like this, or we can flip it. 00:03:29.420 --> 00:03:37.486 And so we can say 1 mole, for every 134.45 grams. 00:03:37.486 --> 00:03:41.680 Both of these are ways to express the relationship between grams and 00:03:41.680 --> 00:03:44.540 moles for copper chloride. 00:03:44.540 --> 00:03:49.468 Now that I know how to go between grams and moles, because of conversion factor, 00:03:49.468 --> 00:03:58.160 I can take 152.5 grams and I can multiply it by one of these two conversion factors. 00:03:58.160 --> 00:03:59.680 I wanna use the one, 00:03:59.680 --> 00:04:03.978 that gets rid of grams from the top of the equation up here. 00:04:03.978 --> 00:04:05.160 Since grams is on the top, 00:04:05.160 --> 00:04:09.050 I'm gonna choose this conversion factor with grams down here. 00:04:09.050 --> 00:04:14.000 So now grams cancels out, grams cancels out, I'm left with moles. 00:04:14.000 --> 00:04:19.720 And I'm gonna do 152.5 times 1 divided by 134.45. 00:04:19.720 --> 00:04:27.660 And that is gonna give me 1.134 moles. 00:04:27.660 --> 00:04:31.540 I'm rounding to four significant figures here because I have one, two, three, 00:04:31.540 --> 00:04:35.760 four significant figures and I don't worry about the 1 cuz it's part of a definition. 00:04:35.760 --> 00:04:41.349 So now I know that I have 1.134 moles of CuCl2. 00:04:41.349 --> 00:04:43.919 Now I can go ahead and calculate the molarity. 00:04:43.919 --> 00:04:47.302 So molarity is going to be moles of solute, 00:04:47.302 --> 00:04:56.399 1.134 moles divided by liters of solution equals 2.25 liters. 00:04:56.399 --> 00:04:59.825 And I wanna crank through that, rounding it to three significant figures, 00:04:59.825 --> 00:05:06.640 cuz I have three sig figs there, it's gonna be 0.504 M. 00:05:06.640 --> 00:05:09.741 And as I said before, don't forget that what that 00:05:09.741 --> 00:05:18.436 means is that there are 0.504 moles of CuCl2 for 00:05:18.436 --> 00:05:23.380 every 1 liter of this solution that we're making here. 00:05:23.380 --> 00:05:27.491 A solution has a volume of 375 milliliters and 00:05:27.491 --> 00:05:32.760 contains 42.5 grams of NaCl, sodium chloride. 00:05:32.760 --> 00:05:35.110 What is its molarity? 00:05:35.110 --> 00:05:38.040 This is kind of a challenging question, because there are two things we need to 00:05:38.040 --> 00:05:42.860 calculate molarity, moles of solute and liters of solution. 00:05:42.860 --> 00:05:46.300 We aren't given either of these two things in the problem. 00:05:46.300 --> 00:05:49.555 Okay, instead of moles of solute, we're given grams of solute, 00:05:49.555 --> 00:05:51.131 sodium chloride is the solute. 00:05:51.131 --> 00:05:54.645 So we can't use that right away, we'll have to convert grams to moles. 00:05:54.645 --> 00:05:58.980 And then instead of getting liters of solution, we get milliliters of solution. 00:05:58.980 --> 00:06:00.655 So before we can run this equation, 00:06:00.655 --> 00:06:05.540 we're gonna have to convert milliliters of solution into liters of solution. 00:06:05.540 --> 00:06:08.950 So let's go step by step to show how do we do these conversions and 00:06:08.950 --> 00:06:11.410 then how we can do the molarity at the end. 00:06:11.410 --> 00:06:16.250 The first thing I'm gonna do is I'm gonna take this 42.5 g of sodium chloride and 00:06:16.250 --> 00:06:18.278 turn it into moles of sodium chloride. 00:06:18.278 --> 00:06:23.090 So I'm gonna need to start with a molar mass of sodium chloride. 00:06:23.090 --> 00:06:27.340 We'll look at sodium and chlorine on the periodic table to get their masses. 00:06:27.340 --> 00:06:31.350 And I'm gonna do 22.99 for sodium. 00:06:31.350 --> 00:06:34.230 I only have one sodium, and I only have one chlorine here. 00:06:34.230 --> 00:06:38.200 So I'm just going to do 35.44 here. 00:06:38.200 --> 00:06:40.610 Add those together and 00:06:40.610 --> 00:06:44.740 I'll get the molar mass which I'm gonnabe using as a convergent factor. 00:06:44.740 --> 00:06:51.287 Okay, so I'm going to write this as 58.44 g over 1 mol. 00:06:51.287 --> 00:06:53.495 That's one way to write it, or 00:06:53.495 --> 00:06:59.076 I can flip the conversion factor and 00:06:59.076 --> 00:07:04.097 I can write 1 mol divided by 58.44 g. 00:07:04.097 --> 00:07:07.718 Now I have the two conversion factors that I'll use for 00:07:07.718 --> 00:07:13.954 taking 42.5 grams of sodium chloride, multiplying it by one of these, 00:07:13.954 --> 00:07:20.023 it's gonna be this one cuz I have grams up here grams down there. 00:07:20.023 --> 00:07:22.145 So these cancel out. 00:07:22.145 --> 00:07:28.321 42.5 divided by 58.44. 00:07:28.321 --> 00:07:31.065 And that is going, I'll put the answer down here, and 00:07:31.065 --> 00:07:39.276 that is going to give me 0.727 moles of sodium chloride. 00:07:39.276 --> 00:07:43.590 Now I know how many moles of sodium chloride I have, so I'm halfway there. 00:07:43.590 --> 00:07:45.690 The next thing I have to do is I have to take 00:07:45.690 --> 00:07:52.020 the volume which is 375 milliliters and multiply that by a conversion factor so 00:07:52.020 --> 00:07:55.543 I can change it from milliliters into liters. 00:07:55.543 --> 00:08:00.260 So there are 1,000 milliliters in one liter, 00:08:00.260 --> 00:08:03.590 which means that we can write these two conversion factors. 00:08:03.590 --> 00:08:07.900 I want to use a conversion factor that's going to turn milliliters into liters. 00:08:07.900 --> 00:08:12.460 So since it's on the top here, I will use a version of this conversion factor 00:08:12.460 --> 00:08:15.440 that puts milliliters on the bottom here. 00:08:15.440 --> 00:08:21.177 So, I'll cancel this out, cancel this out, I'll be left with liters. 00:08:21.177 --> 00:08:25.209 And when I do that, 375 divided by 1,000. 00:08:25.209 --> 00:08:30.756 I'm left with 0.375 liters. 00:08:30.756 --> 00:08:32.472 Now I know my liters. 00:08:32.472 --> 00:08:37.130 So now my moles of sodium chloride and my liters of solution. 00:08:37.130 --> 00:08:40.066 And I can finish this by saying molarity equals 00:08:40.066 --> 00:08:48.715 0.727 moles divided by 0.375 liters. 00:08:48.715 --> 00:08:53.885 And I'm going to get 1.94, that's rounded to one, 00:08:53.885 --> 00:08:56.708 two, three significant figures. 00:08:56.708 --> 00:09:02.002 For my molarity, 1.94 are the units. 00:09:02.002 --> 00:09:04.480 And as before, don't forget what this really means. 00:09:04.480 --> 00:09:09.042 It means that for every liter of this solution, there are 1.94 moles. 00:09:09.042 --> 00:09:14.690 1.94 moles per 1 liter of solution. 00:09:14.690 --> 00:09:20.545 So sometimes you won't always be given moles, you won't always be given liters. 00:09:20.545 --> 00:09:25.899 You'll probably have to convert from grams to moles or from milliliters into liters. 00:09:25.899 --> 00:09:28.843 So just make sure you've got your conversion factors set up straight. 00:09:28.843 --> 00:09:34.047 Now, in the next video instead of having moles and liters and calculating molarity, 00:09:34.047 --> 00:09:38.961 you'll be given molarity and then you'll have to use that as a conversion factor 00:09:38.961 --> 00:09:42.670 to move between moles in a solution and liters of a solution.