1 00:00:00,460 --> 00:00:06,128 Calculate the molarity of a solution prepared by dissolving 9.8 moles of solid 2 00:00:06,128 --> 00:00:14,675 NaOH, that's sodium hydroxide, in enough water to make 3.62 liters of solution. 3 00:00:14,675 --> 00:00:17,964 To find molarity, you take moles of solute and 4 00:00:17,964 --> 00:00:21,734 divide it by liters of solution. 5 00:00:21,734 --> 00:00:27,188 So to set our equation up here, we have Molarity = moles of solute, 6 00:00:27,188 --> 00:00:31,057 sodium hydroxide is the solute here cuz it's getting dissolved in water. 7 00:00:31,057 --> 00:00:36,143 And we have 9.8 moles of that, divided by liters 8 00:00:36,143 --> 00:00:42,280 of solution, which is 3.62 liters right here. 9 00:00:42,280 --> 00:00:48,872 So find molarity, 9.8 divided by 3.62, round the answer to 10 00:00:48,872 --> 00:00:54,659 two significant figures cuz I have 9.8 up here, and I get 2.7. 11 00:00:54,659 --> 00:00:57,240 What should the units be for this? 12 00:00:57,240 --> 00:01:04,306 When you find molarity the final answer is in units of molar, capital M. 13 00:01:04,306 --> 00:01:06,976 So this is 2.7 molar. 14 00:01:06,976 --> 00:01:11,085 But what 2.7 molar really means is that 15 00:01:11,085 --> 00:01:16,986 there are 2.7 moles of NaOH, of the solute, 16 00:01:16,986 --> 00:01:21,701 for every one liter of the solution. 17 00:01:21,701 --> 00:01:28,022 So 2.7 M, but don't forget that that means 2.7 moles for 18 00:01:28,022 --> 00:01:33,078 each 1 liter of this solution up here. 19 00:01:33,078 --> 00:01:39,368 You dissolve 152.5 g of CuCl2, that's copper chloride, 20 00:01:39,368 --> 00:01:45,210 in water to make a solution with a final volume of 2.25 liters. 21 00:01:45,210 --> 00:01:47,845 What is it's molarity? 22 00:01:47,845 --> 00:01:49,541 So, for molarity as you know, 23 00:01:49,541 --> 00:01:53,082 we wanna take moles of solute divided by the liters of solution. 24 00:01:53,082 --> 00:01:56,970 CuCl2, copper chloride is also a solute in this case cuz it's getting dissolved in 25 00:01:56,970 --> 00:01:58,556 the water. 26 00:01:58,556 --> 00:02:02,943 But the problem doesn't tell us how many moles of copper chloride we have. 27 00:02:02,943 --> 00:02:06,825 It tells us how many grams of copper chloride we have. 28 00:02:06,825 --> 00:02:12,784 So 152.5, we can't use that number, instead we have to convert 29 00:02:12,784 --> 00:02:17,140 this to moles and then we can plug it into the molarity equation. 30 00:02:17,140 --> 00:02:20,940 So to convert this amount in grams into moles, 31 00:02:20,940 --> 00:02:25,820 the first thing that we've got to start with is the molar mass of copper chloride. 32 00:02:25,820 --> 00:02:29,940 And so to find the molar mass of copper chloride, we got to find copper and 33 00:02:29,940 --> 00:02:36,080 chlorine on the periodic table and take a look at their atomic masses. 34 00:02:36,080 --> 00:02:40,910 So copper, there is one copper atom in copper chloride. 35 00:02:40,910 --> 00:02:47,760 So I'll take the molar mass of copper, 63.55, and then there 36 00:02:47,760 --> 00:02:51,710 are two of these chlorines in copper chloride. 37 00:02:51,710 --> 00:03:01,247 So I wanna take 2 times the molar mass of chlorine which is 35.44. 38 00:03:01,247 --> 00:03:04,395 When I add these together, 39 00:03:04,395 --> 00:03:12,217 I get 134.45 grams 40 00:03:12,217 --> 00:03:14,600 per 1 mole, okay. 41 00:03:14,600 --> 00:03:17,330 That's like the molar mass of it. 42 00:03:17,330 --> 00:03:20,480 Now we're gonna have to use this as a conversion factor, 43 00:03:20,480 --> 00:03:23,110 to go between grams and moles. 44 00:03:23,110 --> 00:03:25,200 So remember that when we have conversion factors like this, 45 00:03:25,200 --> 00:03:27,040 we can always write them in two ways. 46 00:03:27,040 --> 00:03:29,420 We can write it like this, or we can flip it. 47 00:03:29,420 --> 00:03:37,486 And so we can say 1 mole, for every 134.45 grams. 48 00:03:37,486 --> 00:03:41,680 Both of these are ways to express the relationship between grams and 49 00:03:41,680 --> 00:03:44,540 moles for copper chloride. 50 00:03:44,540 --> 00:03:49,468 Now that I know how to go between grams and moles, because of conversion factor, 51 00:03:49,468 --> 00:03:58,160 I can take 152.5 grams and I can multiply it by one of these two conversion factors. 52 00:03:58,160 --> 00:03:59,680 I wanna use the one, 53 00:03:59,680 --> 00:04:03,978 that gets rid of grams from the top of the equation up here. 54 00:04:03,978 --> 00:04:05,160 Since grams is on the top, 55 00:04:05,160 --> 00:04:09,050 I'm gonna choose this conversion factor with grams down here. 56 00:04:09,050 --> 00:04:14,000 So now grams cancels out, grams cancels out, I'm left with moles. 57 00:04:14,000 --> 00:04:19,720 And I'm gonna do 152.5 times 1 divided by 134.45. 58 00:04:19,720 --> 00:04:27,660 And that is gonna give me 1.134 moles. 59 00:04:27,660 --> 00:04:31,540 I'm rounding to four significant figures here because I have one, two, three, 60 00:04:31,540 --> 00:04:35,760 four significant figures and I don't worry about the 1 cuz it's part of a definition. 61 00:04:35,760 --> 00:04:41,349 So now I know that I have 1.134 moles of CuCl2. 62 00:04:41,349 --> 00:04:43,919 Now I can go ahead and calculate the molarity. 63 00:04:43,919 --> 00:04:47,302 So molarity is going to be moles of solute, 64 00:04:47,302 --> 00:04:56,399 1.134 moles divided by liters of solution equals 2.25 liters. 65 00:04:56,399 --> 00:04:59,825 And I wanna crank through that, rounding it to three significant figures, 66 00:04:59,825 --> 00:05:06,640 cuz I have three sig figs there, it's gonna be 0.504 M. 67 00:05:06,640 --> 00:05:09,741 And as I said before, don't forget that what that 68 00:05:09,741 --> 00:05:18,436 means is that there are 0.504 moles of CuCl2 for 69 00:05:18,436 --> 00:05:23,380 every 1 liter of this solution that we're making here. 70 00:05:23,380 --> 00:05:27,491 A solution has a volume of 375 milliliters and 71 00:05:27,491 --> 00:05:32,760 contains 42.5 grams of NaCl, sodium chloride. 72 00:05:32,760 --> 00:05:35,110 What is its molarity? 73 00:05:35,110 --> 00:05:38,040 This is kind of a challenging question, because there are two things we need to 74 00:05:38,040 --> 00:05:42,860 calculate molarity, moles of solute and liters of solution. 75 00:05:42,860 --> 00:05:46,300 We aren't given either of these two things in the problem. 76 00:05:46,300 --> 00:05:49,555 Okay, instead of moles of solute, we're given grams of solute, 77 00:05:49,555 --> 00:05:51,131 sodium chloride is the solute. 78 00:05:51,131 --> 00:05:54,645 So we can't use that right away, we'll have to convert grams to moles. 79 00:05:54,645 --> 00:05:58,980 And then instead of getting liters of solution, we get milliliters of solution. 80 00:05:58,980 --> 00:06:00,655 So before we can run this equation, 81 00:06:00,655 --> 00:06:05,540 we're gonna have to convert milliliters of solution into liters of solution. 82 00:06:05,540 --> 00:06:08,950 So let's go step by step to show how do we do these conversions and 83 00:06:08,950 --> 00:06:11,410 then how we can do the molarity at the end. 84 00:06:11,410 --> 00:06:16,250 The first thing I'm gonna do is I'm gonna take this 42.5 g of sodium chloride and 85 00:06:16,250 --> 00:06:18,278 turn it into moles of sodium chloride. 86 00:06:18,278 --> 00:06:23,090 So I'm gonna need to start with a molar mass of sodium chloride. 87 00:06:23,090 --> 00:06:27,340 We'll look at sodium and chlorine on the periodic table to get their masses. 88 00:06:27,340 --> 00:06:31,350 And I'm gonna do 22.99 for sodium. 89 00:06:31,350 --> 00:06:34,230 I only have one sodium, and I only have one chlorine here. 90 00:06:34,230 --> 00:06:38,200 So I'm just going to do 35.44 here. 91 00:06:38,200 --> 00:06:40,610 Add those together and 92 00:06:40,610 --> 00:06:44,740 I'll get the molar mass which I'm gonnabe using as a convergent factor. 93 00:06:44,740 --> 00:06:51,287 Okay, so I'm going to write this as 58.44 g over 1 mol. 94 00:06:51,287 --> 00:06:53,495 That's one way to write it, or 95 00:06:53,495 --> 00:06:59,076 I can flip the conversion factor and 96 00:06:59,076 --> 00:07:04,097 I can write 1 mol divided by 58.44 g. 97 00:07:04,097 --> 00:07:07,718 Now I have the two conversion factors that I'll use for 98 00:07:07,718 --> 00:07:13,954 taking 42.5 grams of sodium chloride, multiplying it by one of these, 99 00:07:13,954 --> 00:07:20,023 it's gonna be this one cuz I have grams up here grams down there. 100 00:07:20,023 --> 00:07:22,145 So these cancel out. 101 00:07:22,145 --> 00:07:28,321 42.5 divided by 58.44. 102 00:07:28,321 --> 00:07:31,065 And that is going, I'll put the answer down here, and 103 00:07:31,065 --> 00:07:39,276 that is going to give me 0.727 moles of sodium chloride. 104 00:07:39,276 --> 00:07:43,590 Now I know how many moles of sodium chloride I have, so I'm halfway there. 105 00:07:43,590 --> 00:07:45,690 The next thing I have to do is I have to take 106 00:07:45,690 --> 00:07:52,020 the volume which is 375 milliliters and multiply that by a conversion factor so 107 00:07:52,020 --> 00:07:55,543 I can change it from milliliters into liters. 108 00:07:55,543 --> 00:08:00,260 So there are 1,000 milliliters in one liter, 109 00:08:00,260 --> 00:08:03,590 which means that we can write these two conversion factors. 110 00:08:03,590 --> 00:08:07,900 I want to use a conversion factor that's going to turn milliliters into liters. 111 00:08:07,900 --> 00:08:12,460 So since it's on the top here, I will use a version of this conversion factor 112 00:08:12,460 --> 00:08:15,440 that puts milliliters on the bottom here. 113 00:08:15,440 --> 00:08:21,177 So, I'll cancel this out, cancel this out, I'll be left with liters. 114 00:08:21,177 --> 00:08:25,209 And when I do that, 375 divided by 1,000. 115 00:08:25,209 --> 00:08:30,756 I'm left with 0.375 liters. 116 00:08:30,756 --> 00:08:32,472 Now I know my liters. 117 00:08:32,472 --> 00:08:37,130 So now my moles of sodium chloride and my liters of solution. 118 00:08:37,130 --> 00:08:40,066 And I can finish this by saying molarity equals 119 00:08:40,066 --> 00:08:48,715 0.727 moles divided by 0.375 liters. 120 00:08:48,715 --> 00:08:53,885 And I'm going to get 1.94, that's rounded to one, 121 00:08:53,885 --> 00:08:56,708 two, three significant figures. 122 00:08:56,708 --> 00:09:02,002 For my molarity, 1.94 are the units. 123 00:09:02,002 --> 00:09:04,480 And as before, don't forget what this really means. 124 00:09:04,480 --> 00:09:09,042 It means that for every liter of this solution, there are 1.94 moles. 125 00:09:09,042 --> 00:09:14,690 1.94 moles per 1 liter of solution. 126 00:09:14,690 --> 00:09:20,545 So sometimes you won't always be given moles, you won't always be given liters. 127 00:09:20,545 --> 00:09:25,899 You'll probably have to convert from grams to moles or from milliliters into liters. 128 00:09:25,899 --> 00:09:28,843 So just make sure you've got your conversion factors set up straight. 129 00:09:28,843 --> 00:09:34,047 Now, in the next video instead of having moles and liters and calculating molarity, 130 00:09:34,047 --> 00:09:38,961 you'll be given molarity and then you'll have to use that as a conversion factor 131 00:09:38,961 --> 00:09:42,670 to move between moles in a solution and liters of a solution.