1 00:00:00,270 --> 00:00:01,103 - [Instructor] In this video, 2 00:00:01,103 --> 00:00:03,270 we're gonna introduce ourselves to a new way 3 00:00:03,270 --> 00:00:05,100 of visualizing atoms. 4 00:00:05,100 --> 00:00:06,930 And as you can imagine from the title here, 5 00:00:06,930 --> 00:00:09,570 that's going to be Lewis diagrams. 6 00:00:09,570 --> 00:00:11,310 But before I even get into that, 7 00:00:11,310 --> 00:00:13,710 let's do a little bit of review of what we already know 8 00:00:13,710 --> 00:00:15,450 about Bohr models. 9 00:00:15,450 --> 00:00:18,570 So let's say we take an arbitrary element here. 10 00:00:18,570 --> 00:00:20,070 Let's say we take nitrogen. 11 00:00:20,070 --> 00:00:22,890 Nitrogen, by definition, has seven protons. 12 00:00:22,890 --> 00:00:26,040 And so if it's neutral, it's going to have seven electrons. 13 00:00:26,040 --> 00:00:28,740 So a Bohr model for nitrogen, 14 00:00:28,740 --> 00:00:31,860 in our first shell, that first shell is going to look 15 00:00:31,860 --> 00:00:35,700 just like helium and it's going to have two electrons. 16 00:00:35,700 --> 00:00:37,860 So let me draw it like that. 17 00:00:37,860 --> 00:00:40,680 And then in its second shell, 18 00:00:40,680 --> 00:00:45,680 its second shell, it is going to have the remaining five 19 00:00:45,840 --> 00:00:47,880 of the seven electrons. 20 00:00:47,880 --> 00:00:50,220 And we are going to make them unpaired at first. 21 00:00:50,220 --> 00:00:52,590 So one, two, 22 00:00:52,590 --> 00:00:56,610 three, four, and then five. 23 00:00:56,610 --> 00:00:58,560 The reason why I did it this way is, 24 00:00:58,560 --> 00:01:01,650 a full valence shell is going to have eight electrons 25 00:01:01,650 --> 00:01:03,330 or four pairs. 26 00:01:03,330 --> 00:01:05,190 But if the electrons can spread apart, 27 00:01:05,190 --> 00:01:06,330 they like to spread apart. 28 00:01:06,330 --> 00:01:08,520 So that's why I did one, two, three, four, 29 00:01:08,520 --> 00:01:11,190 and then I paired this last one because there's nowhere else 30 00:01:11,190 --> 00:01:13,920 for it to actually go. 31 00:01:13,920 --> 00:01:16,530 Now, I just touched on this issue of valence electrons. 32 00:01:16,530 --> 00:01:18,750 Those are the electrons in your outermost shell, 33 00:01:18,750 --> 00:01:22,680 and they tend to be the ones that are involved in reactions. 34 00:01:22,680 --> 00:01:24,840 So chemists said, "Hey, just for shorthand, 35 00:01:24,840 --> 00:01:27,420 instead of having to draw all of this every time, 36 00:01:27,420 --> 00:01:31,500 why don't we just visualize the valence electrons?" 37 00:01:31,500 --> 00:01:34,590 And so let's do that in this nitrogen example. 38 00:01:34,590 --> 00:01:37,590 So a Lewis diagram, 39 00:01:37,590 --> 00:01:39,870 which is I'm just going to draw right now, 40 00:01:39,870 --> 00:01:42,930 is that simplified visualization 41 00:01:42,930 --> 00:01:45,780 where you write the symbol for that element, 42 00:01:45,780 --> 00:01:48,210 and you just depict its valence electrons. 43 00:01:48,210 --> 00:01:50,790 We just saw that there are five valence electrons 44 00:01:50,790 --> 00:01:53,370 for nitrogen, seven total, but five valence, 45 00:01:53,370 --> 00:01:56,460 five electrons in that outermost shell. 46 00:01:56,460 --> 00:02:00,840 So it is going to be one, two, 47 00:02:00,840 --> 00:02:04,020 three, four, and then five. 48 00:02:04,020 --> 00:02:07,830 So that's a Lewis diagram for a neutral nitrogen atom. 49 00:02:07,830 --> 00:02:10,860 It turns out we can also do this for ions. 50 00:02:10,860 --> 00:02:15,860 So let's say that we had a nitride ion over here. 51 00:02:15,870 --> 00:02:19,020 Now, a nitride ion has gained three electrons. 52 00:02:19,020 --> 00:02:21,810 So it actually has eight valence electrons. 53 00:02:21,810 --> 00:02:23,850 So if you gain three from five, you're going to have eight. 54 00:02:23,850 --> 00:02:26,160 So I'll go one, two, 55 00:02:26,160 --> 00:02:29,010 three, four, five, 56 00:02:29,010 --> 00:02:31,950 six, seven, eight. 57 00:02:31,950 --> 00:02:35,070 And because it gained three electrons from being neutral, 58 00:02:35,070 --> 00:02:38,010 it now has a negative three charge. 59 00:02:38,010 --> 00:02:39,930 And so you'll often see it written like this 60 00:02:39,930 --> 00:02:42,870 where they put brackets around it, 61 00:02:42,870 --> 00:02:45,810 and you would see three minus. 62 00:02:45,810 --> 00:02:48,307 Now, the last thing that you might wonder about is, 63 00:02:48,307 --> 00:02:49,830 "Okay, I kinda understood 64 00:02:49,830 --> 00:02:51,570 how you got the valence electrons for nitrogen. 65 00:02:51,570 --> 00:02:54,750 Is there just some general pattern in the periodic table?" 66 00:02:54,750 --> 00:02:56,820 And the simple answer is yes. 67 00:02:56,820 --> 00:02:58,380 And that's one of the useful things 68 00:02:58,380 --> 00:02:59,310 about the periodic table. 69 00:02:59,310 --> 00:03:01,260 Or as we'll learn, there's many, many other 70 00:03:01,260 --> 00:03:03,330 really interesting things about it. 71 00:03:03,330 --> 00:03:05,820 If you look at the groups, in general, 72 00:03:05,820 --> 00:03:08,190 you're going to have one valence electron 73 00:03:08,190 --> 00:03:11,430 for Group One elements, for this column over here. 74 00:03:11,430 --> 00:03:13,680 You're going to have two valence electrons 75 00:03:13,680 --> 00:03:15,630 for these Group Two elements. 76 00:03:15,630 --> 00:03:16,627 And I know what you're thinking, 77 00:03:16,627 --> 00:03:19,830 "Okay, is just the group the number of valence electrons?" 78 00:03:19,830 --> 00:03:23,790 Well, unfortunately, it doesn't exactly work out that way. 79 00:03:23,790 --> 00:03:25,800 I'm going to skip the transition metals here 80 00:03:25,800 --> 00:03:27,600 because those get a little bit more complicated. 81 00:03:27,600 --> 00:03:29,100 It's a little bit more advanced. 82 00:03:29,100 --> 00:03:31,530 But then if we go over here to, what is this, 83 00:03:31,530 --> 00:03:34,260 Group One, Two, Three, Four, Five, Six, Seven, 84 00:03:34,260 --> 00:03:37,500 Eight, Nine, 10, 11, 12, 13, 85 00:03:37,500 --> 00:03:41,280 Group 13 over here is going to have three valence electrons. 86 00:03:41,280 --> 00:03:44,280 Group 14, four valence electrons. 87 00:03:44,280 --> 00:03:46,980 Five valence electrons in Group 15, 88 00:03:46,980 --> 00:03:49,380 and that's why we saw five valence electrons 89 00:03:49,380 --> 00:03:50,880 for nitrogen here. 90 00:03:50,880 --> 00:03:53,430 Six for Group 16. 91 00:03:53,430 --> 00:03:55,470 Seven for Group 17. 92 00:03:55,470 --> 00:03:58,020 And then 18 for, or sorry, (laughing) 93 00:03:58,020 --> 00:04:02,430 I should say eight valence electrons for Group 18. 94 00:04:02,430 --> 00:04:03,990 So one way to remember it is, 95 00:04:03,990 --> 00:04:06,750 for Groups 13 through 18, 96 00:04:06,750 --> 00:04:09,060 you take the group number and you subtract 10, 97 00:04:09,060 --> 00:04:11,520 and you're going to get the number of valence electrons. 98 00:04:11,520 --> 00:04:13,290 And hopefully that made sense based 99 00:04:13,290 --> 00:04:15,060 on how we were able to figure out the valence electrons 100 00:04:15,060 --> 00:04:17,253 for example nitrogen.