0:00:00.270,0:00:01.103 - [Instructor] In this video, 0:00:01.103,0:00:03.270 we're gonna introduce[br]ourselves to a new way 0:00:03.270,0:00:05.100 of visualizing atoms. 0:00:05.100,0:00:06.930 And as you can imagine[br]from the title here, 0:00:06.930,0:00:09.570 that's going to be Lewis diagrams. 0:00:09.570,0:00:11.310 But before I even get into that, 0:00:11.310,0:00:13.710 let's do a little bit of[br]review of what we already know 0:00:13.710,0:00:15.450 about Bohr models. 0:00:15.450,0:00:18.570 So let's say we take an[br]arbitrary element here. 0:00:18.570,0:00:20.070 Let's say we take nitrogen. 0:00:20.070,0:00:22.890 Nitrogen, by definition,[br]has seven protons. 0:00:22.890,0:00:26.040 And so if it's neutral, it's[br]going to have seven electrons. 0:00:26.040,0:00:28.740 So a Bohr model for nitrogen, 0:00:28.740,0:00:31.860 in our first shell, that[br]first shell is going to look 0:00:31.860,0:00:35.700 just like helium and it's[br]going to have two electrons. 0:00:35.700,0:00:37.860 So let me draw it like that. 0:00:37.860,0:00:40.680 And then in its second shell, 0:00:40.680,0:00:45.680 its second shell, it is going[br]to have the remaining five 0:00:45.840,0:00:47.880 of the seven electrons. 0:00:47.880,0:00:50.220 And we are going to make[br]them unpaired at first. 0:00:50.220,0:00:52.590 So one, two, 0:00:52.590,0:00:56.610 three, four, and then five. 0:00:56.610,0:00:58.560 The reason why I did it this way is, 0:00:58.560,0:01:01.650 a full valence shell is[br]going to have eight electrons 0:01:01.650,0:01:03.330 or four pairs. 0:01:03.330,0:01:05.190 But if the electrons can spread apart, 0:01:05.190,0:01:06.330 they like to spread apart. 0:01:06.330,0:01:08.520 So that's why I did one, two, three, four, 0:01:08.520,0:01:11.190 and then I paired this last one[br]because there's nowhere else 0:01:11.190,0:01:13.920 for it to actually go. 0:01:13.920,0:01:16.530 Now, I just touched on this[br]issue of valence electrons. 0:01:16.530,0:01:18.750 Those are the electrons[br]in your outermost shell, 0:01:18.750,0:01:22.680 and they tend to be the ones[br]that are involved in reactions. 0:01:22.680,0:01:24.840 So chemists said, "Hey,[br]just for shorthand, 0:01:24.840,0:01:27.420 instead of having to draw[br]all of this every time, 0:01:27.420,0:01:31.500 why don't we just visualize[br]the valence electrons?" 0:01:31.500,0:01:34.590 And so let's do that in[br]this nitrogen example. 0:01:34.590,0:01:37.590 So a Lewis diagram, 0:01:37.590,0:01:39.870 which is I'm just going to draw right now, 0:01:39.870,0:01:42.930 is that simplified visualization 0:01:42.930,0:01:45.780 where you write the[br]symbol for that element, 0:01:45.780,0:01:48.210 and you just depict its valence electrons. 0:01:48.210,0:01:50.790 We just saw that there[br]are five valence electrons 0:01:50.790,0:01:53.370 for nitrogen, seven[br]total, but five valence, 0:01:53.370,0:01:56.460 five electrons in that outermost shell. 0:01:56.460,0:02:00.840 So it is going to be one, two, 0:02:00.840,0:02:04.020 three, four, and then five. 0:02:04.020,0:02:07.830 So that's a Lewis diagram[br]for a neutral nitrogen atom. 0:02:07.830,0:02:10.860 It turns out we can also do this for ions. 0:02:10.860,0:02:15.860 So let's say that we had[br]a nitride ion over here. 0:02:15.870,0:02:19.020 Now, a nitride ion has[br]gained three electrons. 0:02:19.020,0:02:21.810 So it actually has[br]eight valence electrons. 0:02:21.810,0:02:23.850 So if you gain three from five,[br]you're going to have eight. 0:02:23.850,0:02:26.160 So I'll go one, two, 0:02:26.160,0:02:29.010 three, four, five, 0:02:29.010,0:02:31.950 six, seven, eight. 0:02:31.950,0:02:35.070 And because it gained three[br]electrons from being neutral, 0:02:35.070,0:02:38.010 it now has a negative three charge. 0:02:38.010,0:02:39.930 And so you'll often see[br]it written like this 0:02:39.930,0:02:42.870 where they put brackets around it, 0:02:42.870,0:02:45.810 and you would see three minus. 0:02:45.810,0:02:48.307 Now, the last thing that[br]you might wonder about is, 0:02:48.307,0:02:49.830 "Okay, I kinda understood 0:02:49.830,0:02:51.570 how you got the valence[br]electrons for nitrogen. 0:02:51.570,0:02:54.750 Is there just some general[br]pattern in the periodic table?" 0:02:54.750,0:02:56.820 And the simple answer is yes. 0:02:56.820,0:02:58.380 And that's one of the useful things 0:02:58.380,0:02:59.310 about the periodic table. 0:02:59.310,0:03:01.260 Or as we'll learn,[br]there's many, many other 0:03:01.260,0:03:03.330 really interesting things about it. 0:03:03.330,0:03:05.820 If you look at the groups, in general, 0:03:05.820,0:03:08.190 you're going to have one valence electron 0:03:08.190,0:03:11.430 for Group One elements,[br]for this column over here. 0:03:11.430,0:03:13.680 You're going to have two valence electrons 0:03:13.680,0:03:15.630 for these Group Two elements. 0:03:15.630,0:03:16.627 And I know what you're thinking, 0:03:16.627,0:03:19.830 "Okay, is just the group the[br]number of valence electrons?" 0:03:19.830,0:03:23.790 Well, unfortunately, it doesn't[br]exactly work out that way. 0:03:23.790,0:03:25.800 I'm going to skip the[br]transition metals here 0:03:25.800,0:03:27.600 because those get a little[br]bit more complicated. 0:03:27.600,0:03:29.100 It's a little bit more advanced. 0:03:29.100,0:03:31.530 But then if we go over[br]here to, what is this, 0:03:31.530,0:03:34.260 Group One, Two, Three,[br]Four, Five, Six, Seven, 0:03:34.260,0:03:37.500 Eight, Nine, 10, 11, 12, 13, 0:03:37.500,0:03:41.280 Group 13 over here is going to[br]have three valence electrons. 0:03:41.280,0:03:44.280 Group 14, four valence electrons. 0:03:44.280,0:03:46.980 Five valence electrons in Group 15, 0:03:46.980,0:03:49.380 and that's why we saw[br]five valence electrons 0:03:49.380,0:03:50.880 for nitrogen here. 0:03:50.880,0:03:53.430 Six for Group 16. 0:03:53.430,0:03:55.470 Seven for Group 17. 0:03:55.470,0:03:58.020 And then 18 for, or sorry, (laughing) 0:03:58.020,0:04:02.430 I should say eight valence[br]electrons for Group 18. 0:04:02.430,0:04:03.990 So one way to remember it is, 0:04:03.990,0:04:06.750 for Groups 13 through 18, 0:04:06.750,0:04:09.060 you take the group number[br]and you subtract 10, 0:04:09.060,0:04:11.520 and you're going to get the[br]number of valence electrons. 0:04:11.520,0:04:13.290 And hopefully that made sense based 0:04:13.290,0:04:15.060 on how we were able to figure[br]out the valence electrons 0:04:15.060,0:04:17.253 for example nitrogen.