1 00:00:07,239 --> 00:00:08,052 What would you say 2 00:00:08,052 --> 00:00:09,579 is the most important discovery 3 00:00:09,579 --> 00:00:11,581 made in the past few centuries? 4 00:00:11,581 --> 00:00:12,614 Is it the computer? 5 00:00:12,614 --> 00:00:13,263 The car? 6 00:00:13,263 --> 00:00:14,168 Electricity? 7 00:00:14,168 --> 00:00:16,145 Or maybe the discovery of the atom? 8 00:00:16,145 --> 00:00:19,592 I would argue that it is this chemical reaction: 9 00:00:19,592 --> 00:00:21,213 a nitrogen gas molecule 10 00:00:21,213 --> 00:00:23,297 plus three hydrogen gas molecules 11 00:00:23,297 --> 00:00:26,739 gets you two ammonia gas molecules. 12 00:00:26,739 --> 00:00:28,343 This is the Haber process 13 00:00:28,343 --> 00:00:30,925 of binding nitrogen molecules in the air 14 00:00:30,925 --> 00:00:32,431 to hydrogen molecules, 15 00:00:32,431 --> 00:00:35,564 or turning air into fertilizer. 16 00:00:35,564 --> 00:00:36,806 Without this reaction, 17 00:00:36,806 --> 00:00:39,482 farmers would be capable of producing enough food 18 00:00:39,482 --> 00:00:41,348 for only 4 billion people; 19 00:00:41,348 --> 00:00:44,880 our current population is just over 7 billion people. 20 00:00:44,880 --> 00:00:46,881 So, without the Haber process, 21 00:00:46,881 --> 00:00:51,306 over 3 billion people would be without food. 22 00:00:51,306 --> 00:00:55,025 You see, nitrogen in the form of nitrate, NO3, 23 00:00:55,025 --> 00:00:58,205 is an essential nutrient for plants to survive. 24 00:00:58,205 --> 00:01:00,706 As crops grow, they consume the nitrogen, 25 00:01:00,706 --> 00:01:02,425 removing it from the soil. 26 00:01:02,425 --> 00:01:03,923 The nitrogen can be replenished 27 00:01:03,923 --> 00:01:06,346 through long, natural fertilization processes 28 00:01:06,346 --> 00:01:07,845 like decaying animals, 29 00:01:07,845 --> 00:01:09,679 but humans want to grow food 30 00:01:09,679 --> 00:01:11,680 much faster than that. 31 00:01:11,680 --> 00:01:13,591 Now, here's the frustrating part: 32 00:01:13,591 --> 00:01:16,594 78% of the air is composed of nitrogen, 33 00:01:16,594 --> 00:01:19,396 but crops can't just take nitrogen from the air 34 00:01:19,396 --> 00:01:22,511 because it contains very strong triple bonds, 35 00:01:22,511 --> 00:01:24,643 which crops cannot break. 36 00:01:24,643 --> 00:01:26,643 What Haber did basically 37 00:01:26,643 --> 00:01:27,762 was figure out a way 38 00:01:27,762 --> 00:01:29,529 to take this nitrogen in the air 39 00:01:29,529 --> 00:01:31,281 and put it into the ground. 40 00:01:31,281 --> 00:01:34,864 In 1908, the German chemist Fritz Haber 41 00:01:34,864 --> 00:01:36,176 developed a chemical method 42 00:01:36,176 --> 00:01:39,020 for utilizing the vast supply of nitrogen in the air. 43 00:01:39,020 --> 00:01:39,890 Haber found a method 44 00:01:39,890 --> 00:01:41,594 which took the nitrogen in the air 45 00:01:41,594 --> 00:01:43,046 and bonded it to hydrogen 46 00:01:43,046 --> 00:01:45,242 to form ammonia. 47 00:01:45,242 --> 00:01:47,797 Ammonia can then be injected into the soil, 48 00:01:47,797 --> 00:01:50,506 where it is quickly converted into nitrate. 49 00:01:50,506 --> 00:01:53,001 But if Haber's process was going to be used 50 00:01:53,001 --> 00:01:54,095 to feed the world, 51 00:01:54,095 --> 00:01:55,213 he would need to find a way 52 00:01:55,213 --> 00:01:58,415 to create a lot of this ammonia quickly and easily. 53 00:01:58,415 --> 00:01:59,381 In order to understand 54 00:01:59,381 --> 00:02:01,090 how Haber accomplished this feat, 55 00:02:01,090 --> 00:02:02,179 we need to know something 56 00:02:02,179 --> 00:02:04,397 about chemical equilibrium. 57 00:02:04,397 --> 00:02:06,346 Chemical equilibrium can be achieved 58 00:02:06,346 --> 00:02:09,514 when you have a reaction in a closed container. 59 00:02:09,514 --> 00:02:11,233 For example, let's say you put 60 00:02:11,233 --> 00:02:14,346 hydrogen and nitrogen into a closed container 61 00:02:14,346 --> 00:02:16,158 and allow them to react. 62 00:02:16,158 --> 00:02:17,757 In the beginning of the experiment, 63 00:02:17,757 --> 00:02:20,370 we have a lot of nitrogen and hydrogen, 64 00:02:20,370 --> 00:02:22,006 so the formation of ammonia 65 00:02:22,006 --> 00:02:24,098 proceeds at a high speed. 66 00:02:24,098 --> 00:02:26,680 But as the hydrogen and nitrogen react 67 00:02:26,680 --> 00:02:28,261 and get used up, 68 00:02:28,261 --> 00:02:29,883 the reaction slows down 69 00:02:29,883 --> 00:02:31,842 because there is less nitrogen and hydrogen 70 00:02:31,842 --> 00:02:33,625 in the container. 71 00:02:33,625 --> 00:02:36,347 Eventually, the ammonia molecules reach a point 72 00:02:36,347 --> 00:02:38,058 where they start to decompose 73 00:02:38,058 --> 00:02:41,339 back into the nitrogen and hydrogen. 74 00:02:41,339 --> 00:02:43,063 After a while, they two reactions, 75 00:02:43,063 --> 00:02:45,588 creating and breaking down ammonia, 76 00:02:45,588 --> 00:02:47,634 will reach the same speed. 77 00:02:47,634 --> 00:02:49,341 When these speeds are equal, 78 00:02:49,341 --> 00:02:52,147 we say the reaction has reached equilibrium. 79 00:02:53,146 --> 00:02:55,280 This might sound good, but it's not 80 00:02:55,280 --> 00:02:56,511 when what you want 81 00:02:56,511 --> 00:02:58,817 is to just create a ton of ammonia. 82 00:02:58,817 --> 00:03:00,336 Haber doesn't want the ammonia 83 00:03:00,336 --> 00:03:01,855 to break down at all, 84 00:03:01,855 --> 00:03:03,374 but if you simply leave the reaction 85 00:03:03,374 --> 00:03:04,865 in a closed container, 86 00:03:04,865 --> 00:03:06,487 that's what will happen. 87 00:03:06,487 --> 00:03:08,794 Here's where Henry Le Chatelier, 88 00:03:08,794 --> 00:03:09,981 a French chemist, 89 00:03:09,981 --> 00:03:11,271 can help. 90 00:03:11,271 --> 00:03:12,705 What he found was 91 00:03:12,705 --> 00:03:14,590 that if you take a system in equilibrium 92 00:03:14,590 --> 00:03:16,296 and you add something to it, 93 00:03:16,296 --> 00:03:17,723 like, say, nitrogen, 94 00:03:17,723 --> 00:03:18,715 the system will work 95 00:03:18,715 --> 00:03:20,921 to get back to equilibrium again. 96 00:03:20,921 --> 00:03:22,296 Le Chatelier also found 97 00:03:22,296 --> 00:03:23,469 that if you increase 98 00:03:23,469 --> 00:03:25,596 the amount of pressure on a system, 99 00:03:25,596 --> 00:03:26,761 the system tries to work 100 00:03:26,761 --> 00:03:28,978 to return to the pressure it had. 101 00:03:28,978 --> 00:03:30,675 It's like being in a crowded room. 102 00:03:30,675 --> 00:03:32,182 The more molecules there are, 103 00:03:32,182 --> 00:03:33,773 the more pressure there is. 104 00:03:33,773 --> 00:03:35,529 If we look back at our equation, 105 00:03:35,529 --> 00:03:37,532 we see that on the left-hand side, 106 00:03:37,532 --> 00:03:39,681 there are four molecules on the left 107 00:03:39,681 --> 00:03:41,776 and just two on the right. 108 00:03:41,776 --> 00:03:44,278 So, if we want the room to be less crowded, 109 00:03:44,278 --> 00:03:45,872 and therefore have less pressure, 110 00:03:45,872 --> 00:03:46,779 the system will start 111 00:03:46,779 --> 00:03:48,670 combining nitrogen and hydrogen 112 00:03:48,670 --> 00:03:51,804 to make the more compact ammonia molecules. 113 00:03:51,804 --> 00:03:53,821 Haber realized that in order to make 114 00:03:53,821 --> 00:03:55,100 large amounts of ammonia, 115 00:03:55,100 --> 00:03:56,604 he would have to create a machine 116 00:03:56,604 --> 00:03:59,600 that would continually add nitrogen and hygrogen 117 00:03:59,600 --> 00:04:01,438 while also increasing the pressure 118 00:04:01,438 --> 00:04:03,314 on the equilibrium system, 119 00:04:03,314 --> 00:04:05,480 which is exactly what he did. 120 00:04:05,480 --> 00:04:08,030 Today, ammonia is one of the most produced 121 00:04:08,030 --> 00:04:10,313 chemical compounds in the world. 122 00:04:10,313 --> 00:04:14,891 Roughly 131 million metric tons are produced a year, 123 00:04:14,891 --> 00:04:18,314 which is about 290 billion pounds of ammonia. 124 00:04:18,314 --> 00:04:19,363 That's about the mass 125 00:04:19,363 --> 00:04:21,447 of 30 million African elephants, 126 00:04:21,447 --> 00:04:24,314 weighing roughly 10,000 pounds each. 127 00:04:24,314 --> 00:04:28,087 80% of this ammonia is used in fertilizer production, 128 00:04:28,087 --> 00:04:29,041 while the rest is used 129 00:04:29,041 --> 00:04:30,937 in industrial and household cleaners 130 00:04:30,937 --> 00:04:33,314 and to produce other nitrogen compounds, 131 00:04:33,314 --> 00:04:35,265 such as nitric acid. 132 00:04:35,265 --> 00:04:36,345 Recent studies have found 133 00:04:36,345 --> 00:04:38,837 that half of the nitrogen from these fertilizers 134 00:04:38,837 --> 00:04:41,147 is not assimilated by plants. 135 00:04:41,147 --> 00:04:42,977 Consequently, the nitrogen is found 136 00:04:42,977 --> 00:04:44,642 as a volatile chemical compound 137 00:04:44,642 --> 00:04:47,695 in the Earth's water supplies and atmosphere, 138 00:04:47,695 --> 00:04:49,646 severely damaging our environment. 139 00:04:49,646 --> 00:04:51,475 Of course, Haber did not foresee this problem 140 00:04:51,475 --> 00:04:53,095 when he introduced his invention. 141 00:04:53,095 --> 00:04:54,773 Following his pioneering vision, 142 00:04:54,773 --> 00:04:56,388 scientists today are looking 143 00:04:56,388 --> 00:04:59,054 for a new Haber process of the 21st century, 144 00:04:59,054 --> 00:05:01,029 which will reach the same level of aid 145 00:05:01,029 --> 00:05:03,359 without the dangerous consequences.