1 99:59:59,999 --> 99:59:59,999 What would you say 2 99:59:59,999 --> 99:59:59,999 is the most important discovery 3 99:59:59,999 --> 99:59:59,999 made in the past few centuries? 4 99:59:59,999 --> 99:59:59,999 Is it the computer? 5 99:59:59,999 --> 99:59:59,999 The car? 6 99:59:59,999 --> 99:59:59,999 Electricity? 7 99:59:59,999 --> 99:59:59,999 Or maybe the discovery of the atom? 8 99:59:59,999 --> 99:59:59,999 I would argue that it is this chemical reaction: 9 99:59:59,999 --> 99:59:59,999 a nitrogen gas molecule 10 99:59:59,999 --> 99:59:59,999 plus three hydrogen gas molecules 11 99:59:59,999 --> 99:59:59,999 gets you two ammonia gas molecules. 12 99:59:59,999 --> 99:59:59,999 This is the Haber process 13 99:59:59,999 --> 99:59:59,999 of binding nitrogen molecules in the air 14 99:59:59,999 --> 99:59:59,999 to hydrogen molecules, 15 99:59:59,999 --> 99:59:59,999 or turning air into fertilizer. 16 99:59:59,999 --> 99:59:59,999 Without this reaction, 17 99:59:59,999 --> 99:59:59,999 farmers would be capable of producing enough food 18 99:59:59,999 --> 99:59:59,999 for only 4 billion people; 19 99:59:59,999 --> 99:59:59,999 our current population is just over 7 billion people. 20 99:59:59,999 --> 99:59:59,999 So, without the Haber process, 21 99:59:59,999 --> 99:59:59,999 over 3 billion people would be without food. 22 99:59:59,999 --> 99:59:59,999 You see, nitrogen in the form of nitrate, NO3, 23 99:59:59,999 --> 99:59:59,999 is an essential nutrient for plants to survive. 24 99:59:59,999 --> 99:59:59,999 As crops grow, they consume the nitrogen, 25 99:59:59,999 --> 99:59:59,999 removing it from the soil. 26 99:59:59,999 --> 99:59:59,999 The nitrogen can be replenished 27 99:59:59,999 --> 99:59:59,999 through long, natural fertilization processes 28 99:59:59,999 --> 99:59:59,999 like decaying animals, 29 99:59:59,999 --> 99:59:59,999 but humans want to grow food 30 99:59:59,999 --> 99:59:59,999 much faster than that. 31 99:59:59,999 --> 99:59:59,999 Now, here's the frustrating part: 32 99:59:59,999 --> 99:59:59,999 78% of the air is composed of nitrogen, 33 99:59:59,999 --> 99:59:59,999 but crops can't just take nitrogen from the air 34 99:59:59,999 --> 99:59:59,999 because it contains very strong triple bonds, 35 99:59:59,999 --> 99:59:59,999 which crops cannot break. 36 99:59:59,999 --> 99:59:59,999 What Haber did basically 37 99:59:59,999 --> 99:59:59,999 was figure out a way 38 99:59:59,999 --> 99:59:59,999 to take this nitrogen in the air 39 99:59:59,999 --> 99:59:59,999 and put it into the ground. 40 99:59:59,999 --> 99:59:59,999 In 1908, the German chemist Fritz Haber 41 99:59:59,999 --> 99:59:59,999 developed a chemical method 42 99:59:59,999 --> 99:59:59,999 for utilizing the vast supply of nitrogen in the air. 43 99:59:59,999 --> 99:59:59,999 Haber found a method 44 99:59:59,999 --> 99:59:59,999 which took the nitrogen from the air 45 99:59:59,999 --> 99:59:59,999 and bonded it to hydrogen 46 99:59:59,999 --> 99:59:59,999 to form ammonia. 47 99:59:59,999 --> 99:59:59,999 Ammonia can then be injected into the soil, 48 99:59:59,999 --> 99:59:59,999 where it is quickly converted into nitrate. 49 99:59:59,999 --> 99:59:59,999 But if Haber's process was going to be used 50 99:59:59,999 --> 99:59:59,999 to feed the world, 51 99:59:59,999 --> 99:59:59,999 he would need to find a way 52 99:59:59,999 --> 99:59:59,999 to create a lot of this ammonia quickly and easily. 53 99:59:59,999 --> 99:59:59,999 In order to understand 54 99:59:59,999 --> 99:59:59,999 how Haber accomplished this feat, 55 99:59:59,999 --> 99:59:59,999 we need to know something 56 99:59:59,999 --> 99:59:59,999 about chemical equilibrium. 57 99:59:59,999 --> 99:59:59,999 Chemical equilibrium can be achieved 58 99:59:59,999 --> 99:59:59,999 when you have a reaction in a closed container. 59 99:59:59,999 --> 99:59:59,999 For example, let's say you put 60 99:59:59,999 --> 99:59:59,999 hydrogen and nitrogen into a closed container 61 99:59:59,999 --> 99:59:59,999 and allow them to react. 62 99:59:59,999 --> 99:59:59,999 In the beginning of the experiment, 63 99:59:59,999 --> 99:59:59,999 you have a lot of nitrogen and hydrogen, 64 99:59:59,999 --> 99:59:59,999 so the formation of ammonia proceeds a high speed. 65 99:59:59,999 --> 99:59:59,999 But as the hydrogen and nitrogen react 66 99:59:59,999 --> 99:59:59,999 and get used up, 67 99:59:59,999 --> 99:59:59,999 the reaction slows down 68 99:59:59,999 --> 99:59:59,999 because there is less hydrogen and nitrogen 69 99:59:59,999 --> 99:59:59,999 in the container. 70 99:59:59,999 --> 99:59:59,999 Eventually, the ammonia molecules reach a point 71 99:59:59,999 --> 99:59:59,999 where they start to decompose 72 99:59:59,999 --> 99:59:59,999 into the hydrogen and nitrogen. 73 99:59:59,999 --> 99:59:59,999 After a while, they two reactions, 74 99:59:59,999 --> 99:59:59,999 creating and breaking down ammonia, 75 99:59:59,999 --> 99:59:59,999 will reach the same speed. 76 99:59:59,999 --> 99:59:59,999 When these speeds are equal, 77 99:59:59,999 --> 99:59:59,999 we say the reaction has reached equilibrium. 78 99:59:59,999 --> 99:59:59,999 This might sound good, but it's not 79 99:59:59,999 --> 99:59:59,999 when what you want 80 99:59:59,999 --> 99:59:59,999 is to just create a ton of ammonia. 81 99:59:59,999 --> 99:59:59,999 Haber doesn't want the ammonia to break down at all, 82 99:59:59,999 --> 99:59:59,999 but if you simply leave the reaction 83 99:59:59,999 --> 99:59:59,999 in a closed container, 84 99:59:59,999 --> 99:59:59,999 that's what will happen. 85 99:59:59,999 --> 99:59:59,999 Here's where Henry Le Chatelier, 86 99:59:59,999 --> 99:59:59,999 a French chemist, 87 99:59:59,999 --> 99:59:59,999 can help. 88 99:59:59,999 --> 99:59:59,999 What he found was 89 99:59:59,999 --> 99:59:59,999 that if you take a system in equilibrium 90 99:59:59,999 --> 99:59:59,999 and you add something to it, 91 99:59:59,999 --> 99:59:59,999 like, say, nitrogen, 92 99:59:59,999 --> 99:59:59,999 the system will work 93 99:59:59,999 --> 99:59:59,999 to get back to equilibrium again. 94 99:59:59,999 --> 99:59:59,999 Le Chatelier also found 95 99:59:59,999 --> 99:59:59,999 that if you increase 96 99:59:59,999 --> 99:59:59,999 the amount of pressure on a system, 97 99:59:59,999 --> 99:59:59,999 the system tries to work 98 99:59:59,999 --> 99:59:59,999 to return the pressure it had. 99 99:59:59,999 --> 99:59:59,999 It's like being in a crowded room. 100 99:59:59,999 --> 99:59:59,999 The more molecules there are, 101 99:59:59,999 --> 99:59:59,999 the more pressure there is. 102 99:59:59,999 --> 99:59:59,999 If we look back at our equation, 103 99:59:59,999 --> 99:59:59,999 we see that on the left-hand side, 104 99:59:59,999 --> 99:59:59,999 there are four molecules on the left 105 99:59:59,999 --> 99:59:59,999 and just two on the right. 106 99:59:59,999 --> 99:59:59,999 So, if we want the room to be less crowded, 107 99:59:59,999 --> 99:59:59,999 and therefore have less pressure, 108 99:59:59,999 --> 99:59:59,999 the system will start combining 109 99:59:59,999 --> 99:59:59,999 nitrogen and hydrogen 110 99:59:59,999 --> 99:59:59,999 to make the more compact ammonia molecules. 111 99:59:59,999 --> 99:59:59,999 Haber realized that in order to make 112 99:59:59,999 --> 99:59:59,999 large amounts of ammonia, 113 99:59:59,999 --> 99:59:59,999 he would have to create a machine 114 99:59:59,999 --> 99:59:59,999 that would continually add nitrogen and hygrogen 115 99:59:59,999 --> 99:59:59,999 while also increasing the pressure 116 99:59:59,999 --> 99:59:59,999 on the equilibrium system, 117 99:59:59,999 --> 99:59:59,999 which is exactly what he did. 118 99:59:59,999 --> 99:59:59,999 Today, ammonia is one of the most produced 119 99:59:59,999 --> 99:59:59,999 chemical compounds in the world. 120 99:59:59,999 --> 99:59:59,999 Roughly 131 million metric tons are produced a year, 121 99:59:59,999 --> 99:59:59,999 which is about 290 billion pounds of ammonia. 122 99:59:59,999 --> 99:59:59,999 That's about the mass 123 99:59:59,999 --> 99:59:59,999 of 30 million African elephants, 124 99:59:59,999 --> 99:59:59,999 weighing roughly 10,000 pounds each. 125 99:59:59,999 --> 99:59:59,999 80% of this ammonia is used in fertilizer production, 126 99:59:59,999 --> 99:59:59,999 while the rest is used 127 99:59:59,999 --> 99:59:59,999 in industrial and household cleaners 128 99:59:59,999 --> 99:59:59,999 and to produce other nitrogen compounds, 129 99:59:59,999 --> 99:59:59,999 such as nitric acid. 130 99:59:59,999 --> 99:59:59,999 Recent studies have found 131 99:59:59,999 --> 99:59:59,999 that half of nitrogen from these fertilizers 132 99:59:59,999 --> 99:59:59,999 is not assimilated by plants. 133 99:59:59,999 --> 99:59:59,999 Consequently, the nitrogen is found 134 99:59:59,999 --> 99:59:59,999 as a volatile chemical compound 135 99:59:59,999 --> 99:59:59,999 in the Earth's water supply and atmosphere, 136 99:59:59,999 --> 99:59:59,999 severely damaging our environment. 137 99:59:59,999 --> 99:59:59,999 Of course, Haber did not foresee this problem 138 99:59:59,999 --> 99:59:59,999 when he introduced his invention. 139 99:59:59,999 --> 99:59:59,999 Following his pioneering vision, 140 99:59:59,999 --> 99:59:59,999 scientists today are looking 141 99:59:59,999 --> 99:59:59,999 for a new process of the 21st century, 142 99:59:59,999 --> 99:59:59,999 which will reach the same level of aid