WEBVTT 00:00:14.502 --> 00:00:16.560 How come some insects are able to walk 00:00:16.560 --> 00:00:18.135 on the surface of a pond, 00:00:18.135 --> 00:00:19.815 but you quickly sink to the bottom 00:00:19.815 --> 00:00:21.417 when you try to walk on water? 00:00:21.417 --> 00:00:24.811 And why do lakes freeze from the top down in winter? 00:00:24.811 --> 00:00:28.823 In a word, the answer to all these questions is polarity. 00:00:28.823 --> 00:00:30.490 Water is a simple molecule 00:00:30.490 --> 00:00:33.946 made up of one oxygen atom and two hydrogen atoms, 00:00:33.946 --> 00:00:35.862 but it is essential to life. 00:00:35.862 --> 00:00:39.324 In fact, water makes up approximately 60% 00:00:39.324 --> 00:00:41.954 of the adult human being's body weight. 00:00:41.954 --> 00:00:44.372 The polarity within those water molecules 00:00:44.372 --> 00:00:46.624 gives this common substance the properties 00:00:46.624 --> 00:00:49.413 that make it unique and life-sustaining. 00:00:49.413 --> 00:00:51.545 Polarity refers to the unequal sharing 00:00:51.545 --> 00:00:53.604 of electrons within a molecule. 00:00:53.604 --> 00:00:56.551 For water, the bonding between the oxygen atom 00:00:56.551 --> 00:00:59.635 and two hydrogen atoms within a single water molecule 00:00:59.635 --> 00:01:03.020 is like a tug-of-war between a big, strong football player 00:01:03.020 --> 00:01:05.189 and a cute little toddler. 00:01:05.189 --> 00:01:07.063 Oxygen is a larger atom, 00:01:07.063 --> 00:01:09.772 with more protons in its nucleus than hydrogen. 00:01:09.772 --> 00:01:13.170 These positive charges are like a person's physical strength. 00:01:13.170 --> 00:01:14.485 They're able to attract 00:01:14.485 --> 00:01:16.855 the negatively charged electrons in the bond, 00:01:16.855 --> 00:01:19.450 just like a strong individual is able to overpower 00:01:19.450 --> 00:01:22.021 a weaker individual in a tug of war. 00:01:22.021 --> 00:01:24.204 So, oxygen is able to attract 00:01:24.204 --> 00:01:27.123 more than its fair share of electrons. 00:01:27.123 --> 00:01:30.273 Because hydrogen is smaller and has less strength, 00:01:30.273 --> 00:01:31.550 or fewer protons, 00:01:31.550 --> 00:01:33.547 it loses the tug of war 00:01:33.547 --> 00:01:36.733 and attracts fewer than its fair share of electrons. 00:01:36.733 --> 00:01:39.720 So, the oxygen in water behaves as though it's negative, 00:01:39.720 --> 00:01:43.139 and the hydrogens behave as though they're positive. 00:01:43.139 --> 00:01:45.846 The bonds within a single water molecule 00:01:45.846 --> 00:01:48.163 are called polar covalent bonds. 00:01:48.163 --> 00:01:50.859 Covalent means that the electrons are shared. 00:01:50.859 --> 00:01:52.945 But, as we just learned, 00:01:52.945 --> 00:01:56.277 polar means that these electrons are not shared equally. 00:01:56.277 --> 00:01:58.938 In water, the oxygen acts negative 00:01:58.938 --> 00:02:01.655 and the hydrogens act positive. 00:02:01.655 --> 00:02:03.701 Since negative and positive attract, 00:02:03.701 --> 00:02:06.495 that oxygen is attracted to the hydrogen atoms 00:02:06.495 --> 00:02:08.149 in neighboring water molecules. 00:02:08.149 --> 00:02:11.932 A special type of bond forms between water molecules, 00:02:11.932 --> 00:02:13.962 known as a hydrogen bond. 00:02:13.962 --> 00:02:16.770 Hydrogen bonds don't just happen in water either. 00:02:16.770 --> 00:02:18.961 They can form between a water molecule 00:02:18.961 --> 00:02:22.470 and different substances that are polar or ionic. 00:02:22.470 --> 00:02:25.602 Water's ability to stick to itself is called cohesion, 00:02:25.602 --> 00:02:28.323 while water's ability to stick to other substances 00:02:28.323 --> 00:02:30.560 is called adhesion. 00:02:30.560 --> 00:02:32.987 Now, think back to the initial questions. 00:02:32.987 --> 00:02:36.903 First, why are some insects able to walk on water? 00:02:36.903 --> 00:02:39.571 Surface tension due to hydrogen bonding 00:02:39.571 --> 00:02:41.698 creates a thin film on the surface of water 00:02:41.698 --> 00:02:43.159 that gives enough resistance 00:02:43.159 --> 00:02:45.586 for super-light insects to walk on. 00:02:45.586 --> 00:02:46.769 You can't walk on it 00:02:46.769 --> 00:02:48.805 because the hydrogen bonds aren't strong enough 00:02:48.805 --> 00:02:50.545 to hold you up. 00:02:50.545 --> 00:02:52.918 Why does ice float on top of liquid water? 00:02:52.918 --> 00:02:54.685 For most other substances, 00:02:54.685 --> 00:02:57.888 the solid state is more dense than the liquid state, 00:02:57.888 --> 00:03:00.390 but that is not the case for water! 00:03:00.390 --> 00:03:02.599 Hydrogen bonds keep water molecules 00:03:02.599 --> 00:03:05.554 farther apart in frozen water than in liquid water. 00:03:05.554 --> 00:03:07.518 The farther apart the molecules are, 00:03:07.518 --> 00:03:09.773 the less dense that solid is. 00:03:09.773 --> 00:03:13.227 So ice is about 9% less dense than water, 00:03:13.227 --> 00:03:15.441 which means it floats on the top. 00:03:15.441 --> 00:03:17.943 That's why lakes freeze from the top down 00:03:17.943 --> 00:03:19.861 and aquatic life is able to survive 00:03:19.861 --> 00:03:21.947 through a cold winter every year. 00:03:21.947 --> 00:03:24.656 It is the polarity of the water molecule 00:03:24.656 --> 00:03:26.907 and the resulting hydrogen bonding 00:03:26.907 --> 00:03:29.996 that account for water's unique properties. 00:03:29.996 --> 00:03:33.127 So, the reason that water is so special, 00:03:33.127 --> 00:03:34.440 from inside your cells 00:03:34.440 --> 00:03:35.877 to the world's oceans, 00:03:35.877 --> 00:03:40.826 is simply because it is a polar molecule.